DOI: https://doi.org/10.9767/bcrec.14.3.4251.689-696

Optimization of Monoglycerides Production Using KF/CaO-MgO Heterogeneous Catalysis

Department of Chemical Engineering, Diponegoro University, Indonesia

Received: 25 Jan 2019; Revised: 28 May 2019; Accepted: 29 May 2019; Available online: 30 Sep 2019; Published: 1 Dec 2019.
Editor(s): Luqman Buchori
Open Access Copyright (c) 2019 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.
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Abstract

The production of monoglyceride or monoacylglycerol (MAG) from triglycerides and glycerol has been studied. The purpose of this research was to study the effect of using KF/CaO-MgO catalyst on MAG production with batch reactor. The effect of reaction temperature, reaction time, and catalyst loading was investigated using Response Surface Methods (RSM). The reaction temperature, reaction time, and catalyst loading were varied at 200-220 ºC,  2-4 hours, and 0.1-0.3 % w/w, respectively. The maximum yield of monoglyceride 41.58% was achieved the optimum conditions of  catalyst loading of 0.19 % (w/w), reaction temperature of 208.4 ºC, and reaction time of 3.20 hours. 

 

Keywords: KF/Ca-MgO Catalyst; Monoglyceride; Optimization; Response Surface Method
Funding: Diponegoro University for the financial support received with Project No: 474–103/VN7.P43/PP/2018

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Section: The 3rd International Conference on Chemical and Material Engineering 2018 (ICCME 2018)
Language : EN
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  20. Cornell, J.A. (1991). Experiments with Mixtures: Designs, Models, and the Analysis of Mixture Data, Journal of the American Statistical Association, 86(415): 56–57
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  22. Coker, A.K. (2001). Modeling of Chemical Kinetics and Reactor Design, 1st edition, Gulf Publishing Company, United States of America
  23. Thanh, L.T., Okitsu, K., Boi, L.V., Maeda, Y. (2012). Catalytic Technologies for Biodiesel Fuel Production and Utilization of Glycerol: A Review, Catalysts, 2: 191-222
  24. Prakoso, T., Sukanti, M.M. (2007). Production of Monoglycerides, Indonesian Journal of Chemical Engineering, 6(3): 689–697

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