skip to main content

Enhanced Adsorption of Brilliant Green Dye Using Barium Ferrite/Graphene Oxide Nanocomposites

1Chemical Engineering Department, College of Engineering, Al-Nahrain University, Baghdad, Iraq

2Scientific Research Commission, Ministry of Higher Education and Scientific Research, Baghdad, Iraq

3Department of Engineering and Computer Science, McNeese State University, Lake Charles 70605, LA, United States

4 Chemical Engineering Department, Faculty of Engineering, Alexandria University, Alexandria 21544, Egypt

View all affiliations
Received: 25 Jul 2025; Revised: 5 Oct 2025; Accepted: 7 Oct 2025; Available online: 12 Oct 2025; Published: 26 Dec 2025.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2025 by Authors, Published by BCREC Publishing Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Fulltext View|Download

Citation Format:
Cover Image
Abstract

This study presents the synthesis and characterization of barium ferrite/graphene oxide (BaFeO/GO) nanocomposites for the adsorption of brilliant green dye (BGD) from aqueous solutions. BaFeO/GO nanocomposites were fabricated via a co-precipitation method with varying GO content (10-30 wt%), and characterized using Fourier Transform Infra rEd (FTIR), X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Field-Emission Scanning Electron Microscopy (FESEM), Transmission Electron Microscope (TEM), Brunauer, Emmett, and Teller (BET), and Vibrating Sample Magnetometer (VSM) techniques. The incorporation of GO enhanced the surface area, reduced BaFeO nanoparticle agglomeration, and introduced additional oxygen-containing functional groups, significantly improving the adsorption performance. Batch adsorption experiments were conducted to evaluate the effects of pH, contact time, adsorbent dose, and initial dye concentration. The maximum dye removal efficiency reached 98.9% with the BaFeO/30%GO composite. Kinetic studies showed excellent agreement with the pseudo-second-order model, while adsorption isotherm analysis indicated that the Langmuir model best fit the equilibrium data, suggesting monolayer adsorption. These results demonstrate the potential of BaFeO/GO nanocomposites as efficient, magnetically separable adsorbents for the removal of cationic dyes from wastewater. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).


 
Keywords: Wastewater Treatment; Adsorption; Graphene Oxide Nanocomposites; Brilliant Green Dye

Article Metrics:

  1. Gregory, P. (2000) Dyes and dye intermediates. Kirk‐Othmer Encyclopedia of Chemical Technology, p. 1-66. DOI: 10.1002/0471238961.0425051907180507.a01.pub2
  2. Dave, S., Das, J., Varshney, B., Sharma, V.P. (2022) Dyes and pigments: Interventions and how safe and sustainable are colors of life, in Trends and Contemporary Technologies for Photocatalytic Degradation of Dyes. Springer. p. 1-20. DOI: 10.1007/978-3-031-08991-6_1
  3. Mansour, R.A.E.-G., Simeda, M.G., Zaatout, A.A. (2021) Removal of brilliant green dye from synthetic wastewater under batch mode using chemically activated date pit carbon. RSC Advances, 11(14), 7851-7861. DOI: 10.1039/D0RA08488C
  4. Aqeel, K., Mubarak, H.A., Amoako-Attah, J., Abdul-Rahaim, L.A., Al Khaddar, R., Abdellatif, M., Al-Janabi, A., Hashim, K.S. (2020) Electrochemical removal of brilliant green dye from wastewater. IOP Conference Series: Materials Science and Engineering. IOP Publishing. DOI: 10.1088/1757-899X/888/1/012036
  5. Booton, A., Mayer, B.K., Zitomer, D.H. (2024) Chemical oxidation as an alternative for municipal wastewater secondary treatment: a review. Reviews in Environmental Science and Bio/Technology, 23(1), 43-65. DOI: 10.1007/s11157-024-09684-5
  6. Farsang, E., Horváth, K., Beck, A., Wang, Q., Lauber, M., Guillarme, D., Fekete, S. (2020) Impact of the column on effluent pH in cation exchange pH gradient chromatography, a practical study. Journal of Chromatography A, 1626, 461350. DOI: 10.1016/j.chroma.2020.461350
  7. Rane, A., Joshi, S.J. (2021) Biodecolorization and biodegradation of dyes: A review. The Open Biotechnology Journal, 15(1), 97-108. DOI: 10.2174/1874070702115010097
  8. Guo, S., Wang, H., Liu, X., Zhang, Z., Liu, Y. (2024) Approaches for the treatment and resource utilization of electroplating sludge. Materials, 17(7), 1707. DOI: 10.3390/ma17071707
  9. Zeitoun, Z., El-Shazly, A., Sameh, M., Ragab, M., Nosier, S., Moharram, M. (2021) Electrospinning of polyvinylidene fluoride membranes: Effect of membrane composition and fabrication conditions. Egyptian Journal of Chemistry, 65, 41-50. DOI: 10.21608/ejchem.2021.77967.3913
  10. Zeitoun, Z., El-Shazly, A.H., Nosier, S., Elmarghany, M.R., Salem, M.S., Taha, M.M. (2020) Performance Evaluation and Kinetic Analysis of Photocatalytic Membrane Reactor in Wastewater Treatment. Membranes, 10(10), 276. DOI: 10.3390/membranes10100276
  11. Zeitoun, Z., Selem, N.Y. (2023) A comprehensive review on textile wastewater treatment by coupling TiO2 with PVDF membrane. Bulletin of the National Research Centre, 47(1), 153. DOI: 10.1186/s42269-023-01131-9
  12. Ani, P.C., Al-Abedi, H.J., Smith, J.D., Zeitoun, Z. (2025) Comparative Morphological and Thermal Analysis of Biochar from Oak, and from Oak, Pine and RDF Blends, in a Downdraft Gasifier. Fuels, 6(3). 73. DOI: 10.3390/fuels6030073
  13. Ani, P.C., Alhameedi, H., Al-Abedi, H.J., Al-Rubaye, H., Zeitoun, Z., Ewuzie, U., Smith, J.D. (2025) The Comprehensive Quantification and Characterization of Oak Biochar Produced via a Gasification Process Using a Downdraft Reactor. Fuels, 6(3), 51. DOI: 10.3390/fuels6030051
  14. Ani, P.C., Al-Abedi, H.J., Smith, J.D., Zeitoun, Z. (2025) Biochar Surface Chemistry Modification by Blending Hardwood, Softwood, and Refuse-Derived Fuel: Insights from XPS, FTIR, and Zeta Potential Analysis. Fuels, 6(3), 71. DOI: 10.3390/fuels6030071
  15. Kyzas, G.Z., Deliyanni, E.A., Matis, K.A. (2014) Graphene oxide and its application as an adsorbent for wastewater treatment. Journal of Chemical Technology & Biotechnology, 89(2), 196-205. DOI: 10.1002/jctb.4220
  16. Ramesha, G., Kumara, A.V., Muralidhara, H., Sampath, S. (2011) Graphene and graphene oxide as effective adsorbents toward anionic and cationic dyes. Journal of Colloid and Interface Science, 361(1), 270-277. DOI: 10.1016/j.jcis.2011.05.050
  17. Yadav, P., Kapil, I., Dutta, M., Bhaduri, A. (2024) Effectual visible-driven photocatalytic performances on brilliant green dye by reduced graphene oxide–zinc oxide nanocomposite. Ionics, 30(5), 2927-2937. DOI: 10.1007/s11581-024-05450-3
  18. Padidar, A., Mohammadi, A. (2024) Development of a magnetite nanocomposite based on expanded graphite/chitosan for efficient removal of brilliant green dye from aqueous solutions. Separation Science and Technology, 59(6-9), 954-966. DOI: 10.1080/01496395.2024.2358206
  19. Ahmad, I., Athar, M.S., Muneer, M., Altass, H.M., Felemban, R., Ahmed, S.A. (2025) Synergistic design of a graphene oxide-mediated polyaniline/α-Fe2O3 ternary heterostructure: advancing photocatalytic degradation and adsorption efficiency. Nanoscale, 17(7), 3822-3836. DOI: 10.1039/D4NR03681F
  20. Khan, Q., Sayed, M., Gul, I. (2023) Titania/reduced graphene oxide nanocomposites (TiO2/rGO) as an efficient photocatalyst for the effective degradation of brilliant green in aqueous media: effect of peroxymonosulfate and operational parameters. Environmental Science and Pollution Research, 30(27), 71025-71047. DOI: 10.1007/s11356-023-27316-3
  21. Khani, R., Irani, M. (2020) A reusable reduced graphene oxide-cobalt oxide nanocomposite with excellent yield as adsorbent for determination trace-level of brilliant green in environmental water samples. Research on Chemical Intermediates, 46(4), 2137-2154. DOI: 10.1007/s11164-020-04083-1
  22. Hou, Y., Qi, J., Hu, J., Ruan, W., Xiang, Y., Wei, X. (2022) Decolorizing brilliant green by mesoporous Pd–Fe magnetic nanoparticles immobilized on reduced graphene oxide: Artificial neural network modeling. International Journal of Environmental Science and Technology, 19(5), 3935-3946. DOI: 10.1007/s13762-021-03283-5
  23. Bukovska, H., García-Perez, F., Brea Núñez, N., Bonales, L.J., Velasco, A., Clavero, M.Á., Martínez, J., Quejido, A.J., Rucandio, I., Gómez-Mancebo, M.B. (2023) Evaluation and Optimization of Tour Method for Synthesis of Graphite Oxide with High Specific Surface Area. Journal of Carbon Research, 9(3), 65. DOI: 10.3390/c9030065
  24. Rani, S., Kumar, M., Garg, R., Sharma, S., Kumar, D. (2016) Amide functionalized graphene oxide thin films for hydrogen sulfide gas sensing applications. IEEE Sensors Journal, 16(9), 2929-2934. DOI: 10.1109/JSEN.2016.2524204
  25. Bae, H., Ahmad, T., Rhee, I., Chang, Y., Jin, S.-U., Hong, S. (2012) Carbon-coated iron oxide nanoparticles as contrast agents in magnetic resonance imaging. Nanoscale Research Letters, 7, 1-5. DOI: 10.1186/1556-276X-7-44
  26. Sayed, A., Fayed, M.S., Kassem, M., Ezz, T. (2011) Different Factors Affecting the Preparation of Hexagonal Barium Ferrite and its Evaluation by Radar Wave Absorption. in International Conference on Aerospace Sciences and Aviation Technology. International Conference on Aerospace Sciences and Aviation Technology, 14, 1-7. DOI: 10.21608/asat.2011.23276
  27. Hojjati Najafabadi, A., Ghasemi, A., Mozaffarinia, R. (2016) Synthesis and evaluation of microstructural and magnetic properties of Cr3+ substitution barium hexaferrite nanoparticles (BaFe10.5−xAl1.5CrxO19). Journal of Cluster Science, 27, 965-978. DOI: 10.1007/s10876-015-0963-x
  28. Goel, S., Garg, A., Gupta, R.K., Dubey, A., Prasad, N.E., Tyagi, S. (2020) Development of RGO/BaFe12O19-based composite medium for improved microwave absorption applications. Applied Physics A, 126(6), 436. DOI: 10.1007/s00339-020-03613-3
  29. Maddahfar, M., Ramezani, M., Mostafa Hosseinpour-Mashkani, S. (2016) Barium hexaferrite/graphene oxide: controlled synthesis and characterization and investigation of its magnetic properties. Applied Physics A, 122, 1-9. DOI: 10.1007/s00339-016-0283-5
  30. Mane, V.S., Mall, I.D., Srivastava, V.C. (2007) Kinetic and equilibrium isotherm studies for the adsorptive removal of Brilliant Green dye from aqueous solution by rice husk ash. Journal of Environmental Management, 84(4), 390-400
  31. Abate, G.Y., Alene, A.N., Habte, A.T., Getahun, D.M. (2020) Adsorptive removal of malachite green dye from aqueous solution onto activated carbon of Catha edulis stem as a low cost bio-adsorbent. Environmental Systems Research, 9, 1-13. DOI: 10.1186/s40068-020-00191-4
  32. Ai, L., Zhang, C., Liao, F., Wang, Y., Li, M., Meng, L., Jiang, J. (2011) Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: kinetic, isotherm and mechanism analysis. Journal of Hazardous Materials, 198, 282-290. DOI: 10.1016/j.jhazmat.2011.10.041
  33. Bello, O.S., Adegoke, K.A., Akinyunni, O.O. (2017) Preparation and characterization of a novel adsorbent from Moringa oleifera leaf. Applied Water Science, 7, 1295-1305. DOI: 10.1007/s13201-015-0345-4
  34. Abate, G.Y., Alene, A.N., Habte, A.T., Getahun, D.M. (2020) Adsorptive removal of malachite green dye from aqueous solution onto activated carbon of Catha edulis stem as a low cost bio-adsorbent. Environmental Systems Research, 9(1), 29. DOI: 10.1186/s40068-020-00191-4

Last update:

No citation recorded.

Last update:

No citation recorded.