DOI: https://doi.org/10.9767/bcrec.18471

Synthesis, Structural Characterization, Hirschfeld Surface Analysis and Photocatalytic CO2 Reduction of Yb(III) Complex with 4-Aacetylphenoxyacetic Acid and 1,10-Phenanthroline Ligands

1College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China

2College of Chemistry and Chemical Engineering, Weifang University, China

3College of Biology and Oceanography, Weifang University, Weifang 261061, P. R. China, China

4 College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P. R. China, China

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Received: 5 Jun 2023; Revised: 13 Jul 2023; Accepted: 13 Jul 2023; Available online: 16 Jul 2023; Published: 20 Aug 2023.
Editor(s): Rodiansono Rodiansono
Open Access Copyright (c) 2023 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
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Abstract

A new nine-coordinated Yb(III) complex [YbL3(Phen)] (1) (HL = 2-(4-acetylphenoxy)acetic acid (APA), Phen = 1,10-phenanthroline) was synthesized with 2-(4-acetylphenoxy)acetic acid, YbCl3.6H2O, NaOH and 1,10-phenanthroline as materials. Complex (1) was characterized by IR and X-ray single-crystal diffraction analysis. The results show that the Yb(III) ion is nine-coordinated with seven carboxylate oxygen atoms from five different deprotonated APA ligands and two nitrogen atoms from one Phen ligand. Complex (1) forms a 3D supramolecular framework through the - stacking interactions between the Phen aromatic rings. The hirschfeld surface analysis of complex (1) was also calculated. The CO2 photoconversion activity of complex (1) has been performed under UV-vis light irradiation. The complex (1) shows good photocatalytic activity with the yield of CO is closed to 146 mmol/g after three hours of UV-vis light irradiation, the CO selectivity has reached to 97.9%. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Keywords: 2-(4-Acetylphenoxy)acetic acid; Yb(III) complex; Synthesis; Crystal structure; Hirschfeld surface analysis; Photocatalytic CO2 reduction
Funding: National Natural Science Foundation of China under contract No. 21171132; The Natural Science Foundation of Shandong under contract ZR2014BL003; The Project of Shandong Province Higher Educational Science and Technology Program under contract J14LC01; Doctoral Program of Weifang University under contract No. 2021BS09

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Section: Original Research Articles
Language : EN
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