DOI: https://doi.org/10.9767/bcrec.16.1.10309.170-178

Light-Harvesting Metal-Organic Frameworks (MOFs) La-PTC for Photocatalytic Dyes Degradation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Indonesia

Received: 8 Feb 2021; Revised: 20 Mar 2021; Accepted: 21 Mar 2021; Available online: 22 Mar 2021; Published: 31 Mar 2021.
Editor(s): Is Fatimah, Istadi Istadi
Open Access Copyright (c) 2021 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
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Abstract

A novel porous metal organic framework, La-PTC was synthesized by solvothermal method using a perylene-3,4,9,10-tetracarboxylate ligand and lanthanum metal ion. The FTIR analysis showed that La-PTC has a different structure with PTCDA and Na4PTC. The La-PTC MOF has high crystallinity, bandgap energy of 2.21 eV with a maximum absorption area at 561 nm. A rod shape structure of La-PTC has been obtained with the surface area of 22.2364 m2.g−1 and classified into mesoporous material. The La-PTC was relative stable up to 376.93 °C. The La-PTC can degrade 64.76% of MO within ca. 240 min under visible light irradiation with the amount of 30 mg La-PTC. The addition of H2O2 improved the photocatalytic activity of La-PTC with degradation efficiency of 67.02%, 70.00%, and 99.60% for MB, RhB, and MO, respectively. This study presents the fabrication of the light-harvesting metal organic framework, La-PTC and its potential in dyes degradation. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

 

Keywords: Metal-organic frameworks; lanthanum; perylene; dyes degradation; photocatalytic
Funding: Ministry of Research and Technology/National Research and Innovation Agency of Indonesia

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Section: The 3rd International Conference on Chemistry, Chemical Process and Engineering 2020) (IC3PE 2020)
Language : EN
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