skip to main content

Acacia auriculiformis-Derived Cellulose Nanoparticles as a Sustainable Nanofluid for Enhanced Oil Recovery

1Faculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuhraya Persiaran Tun Khalil Yaakob 26300 Kuantan, Pahang, Malaysia, Gambang, Pahang, Malaysia

2School of Computing and Digital Studies, Sheffield Hallam University, Sheffield, England, United Kingdom

3Petroleum Engineering Department, University Teknologi PETRONAS, 32610, Seri Iskandar, Perak Darul Ridzuan, Malaysia

4 Center of Reservoir Dynamics (CORED), Institute of Sustainable Energy, Universiti Teknologi, PETRONAS, 32610, Seri Iskandar, Perak Darul Ridzuan, Malaysia

View all affiliations
Received: 12 Aug 2026; Revised: 3 Sep 2026; Accepted: 5 Sep 2026; Available online: 8 Sep 2026; Published: 26 Dec 2026.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2026 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Fulltext View|Download

Citation Format:
Cover Image
Abstract

Conventional enhanced oil recovery (EOR) methods often lose effectiveness under high-temperature, high-salinity (HTHS) conditions because of inadequate fluid stability, limited wettability alteration, and insufficient interfacial tension (IFT) reduction. This study developed and evaluated cellulose nanoparticles (CNPs) derived from Acacia auriculiformis as a sustainable nanofluid for EOR. CNPs were extracted using a deep eutectic solvent (DES) process and surface-modified to improve thermal stability and interfacial functionality. Structural, morphological, compositional, and thermal characteristics were evaluated, while the resulting cellulose nanofluid (CNF) was assessed through rheology, IFT, contact-angle, and sand-pack flooding experiments. The process yielded 78.3% CNP, with an average particle size of 19.65 ± 0.2 nm and crystallinity index (CrI) of 76.6%, confirming successful formation of crystalline nanocellulose. At 0.2 wt%, CNF reduced oil-water IFT to approximately 7.8 mN/m at elevated temperature and decreased the sandstone contact angle to 16.5°, indicating strong water-wet alteration. Sand-pack flooding achieved 13.7% incremental oil recovery and 72.3% total recovery, compared with 9.8% incremental recovery and 63.1% total recovery for xanthan. The superior performance is attributed to the combined effects of IFT reduction, wettability alteration, mobility control, and thermal stability. Overall, Acacia-derived CNF demonstrates greater EOR potential than xanthan and represents a promising, environmentally sustainable nanofluid for challenging reservoir conditions. Copyright © 2026 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Keywords: Interfacial tension; xanthan; cellulose nanofluid; contact angle; Enhanced oil recovery; Acacia auriculiformis
Funding: Ministry of Higher Education (MOHE) Malaysia; Universiti Malaysia Pahang; RDU230304

Article Metrics:

  1. Zadmehr, M., Perrons, R.K., Desouza, K.C. (2026). The impact of geopolitical risks on the dynamic capabilities of Big Oil. Energy Res. Soc. Sci., 134, 104612. DOI: 10.1016/j.erss.2026.104612
  2. Abutu, D., Yussof, H.W., Nyah, F., Nwaichi, P.I., Umunnawuike, C., Agi, A. (2026). Modelling biohydrogen production from residual hydrocarbons by immobilized bacteria using COMSOL Multiphysics. Biomass Bioenergy, 211, 109165. DOI: 10.1016/j.biombioe.2026.109165
  3. Rezvani, H., Binks, B.P., Nguyen, D. (2024). Surfactant-Nanoparticle Formulations for Enhanced Oil Recovery in Calcite-Rich Rocks. Langmuir, 40(47), 24989–25002. DOI: 10.1021/acs.langmuir.4c03100
  4. Musa, M.S.M., Damin, R., Yekeen, N., Nwaichi, P.I., Umunnawuike, C., Nyah, F., Abutu, D., Money, B., Gbonhinbor, J., Nwaichi, E.O., Agi, A. (2025). Experimental Assessment of the Rheological Behaviours and Enhanced Oil Recovery Potentials of Pectin. SPE Nigeria Annual International Conference and Exhibition, SPE. Aug. 2025. DOI: 10.2118/228639-MS
  5. Chen, X., Li, Y.-Q., Liu, Z.-Y., Trivedi, J., Gao, W.-B., Sui, M.-Y. (2023). Experimental investigation on the enhanced oil recovery efficiency of polymeric surfactant: Matching relationship with core and emulsification ability. Pet. Sci., 20(1), 619–635. DOI: 10.1016/j.petsci.2022.11.002
  6. Sun, X., Bai, B., Alhuraishawy, A.K., Zhu, D. (2021). Understanding the Plugging Performance of HPAM-Cr (III) Polymer Gel for CO2 Conformance Control. SPE Journal, 26(5), 3109–3118. DOI: 10.2118/204229-PA
  7. Marquez, R., Ding, H., Barrios, N., Vera, R. E., Salager, J-L., Al-Shalabi, E.W., Mettu, S. (2025). Recent Advances in Enhanced Oil Recovery with Low-Salinity Waterflooding and Its Hybrid Methods in Carbonate Reservoirs. Energy & Fuels, 39(19), 8769–8799. DOI: 10.1021/acs.energyfuels.4c06023
  8. Hassan, A.M., Al-Shalabi, E.W., Ayoub, M.A. (2022). Updated Perceptions on Polymer-Based Enhanced Oil Recovery toward High-Temperature High-Salinity Tolerance for Successful Field Applications in Carbonate Reservoirs. Polymers (Basel)., 14(10), 2001. DOI: 10.3390/polym14102001
  9. Zhang, G., Ran, Y., Jiang, P., Pei, H. (2023). A Study on the Thermal Degradation of an Acrylamide and 2-Acrylamido-2-Methylpropanesulfonic Acid Copolymer at High Temperatures. Polymers (Basel), 15(12), 2665. DOI: 10.3390/polym15122665
  10. Jing, Z., Liu, C., Qi, R., Ren, P. (2018). Many-body effect determines the selectivity for Ca 2+ and Mg 2+ in proteins. Proceedings of the National Academy of Sciences, 115(32), Aug. 2018. DOI: 10.1073/pnas.1805049115
  11. Nyah, F., Ridzuan, N., Epelle, E., Aziz, M.A.B., Money, B., Abutu, D., Agi, A. (2025). Cellulose bionanomaterial design for enhanced oil recovery: A review of existing, emerging technologies and future outlook. Petroleum Research. 101(2), 641-686. DOI: 10.1016/j.ptlrs.2025.12.002
  12. Ikeagwu, C., Nyah, F.J., Onyekonwu, M.O., Ogolo, N.A., Ubani, C. (2013). Study of Alcohol Mixtures for Enhanced Oil Recovery. SPE Nigeria Annual International Conference and Exhibition, SPE, Aug. 2013. DOI: 10.2118/167547-MS
  13. Umunnawuike, C., Abutu, D., Nwaichi, P.I., Nyah, F., Agi, A. (2026). Thermophilic biohydrogen production from reservoir residual hydrocarbons using palm oil mill effluent–derived microbial consortia. Science of The Total Environment, 1016, 181482, Feb. 2026. DOI: 10.1016/j.scitotenv.2026.181482
  14. Khormali, A., Ahmadi, S. (2026). Optimization of HPAM Polymer Flooding for Enhanced Oil Recovery Through Experimental Core Flooding and Predictive Statistical Modeling, Polymers (Basel), 18(13), 1640. DOI: 10.3390/polym18131640
  15. Cancela, B.R., Palermo, L.C.M., de Oliveira, P.F., Mansur, C.R.E. (2022). Rheological study of polymeric fluids based on HPAM and fillers for application in EOR. Fuel, 330, 125647, Dec. 2022, DOI: 10.1016/j.fuel.2022.125647
  16. Sarokolai, F.T., Shiri, Y. (2025). Titanium dioxide-grafted polyacrylamide nanocomposites ameliorate the rheology and high-pressure high-temperature fluid loss of water-based drilling fluids. Results in Engineering, 27, 106624. DOI: 10.1016/j.rineng.2025.106624
  17. Ali, I., Han, S., Tian, L., Huang, C., Zhazitov, M., Duisebayev, T., Sagidolda, Y., Ali, M.Z., Toktarbaiuly, O., Xu, Y., Liu, J. (2026). Advancements in polymeric superhydrophobic nanocomposite coatings: From synthesis to industrial applications. Review of Materials Research, 2(5), p100202, May 2026, DOI: 10.1016/j.revmat.2026.100202
  18. Mondal, M.C., Uddin, H.M.W., Progoti, Q.R.M., Tushar, M.A-N., Dutta, A., Saif, T., Malitha, S.B. (2026). Enhanced oil recovery via metal oxide nanoparticles: A review of recent advancements, core mechanisms, and future outlook. Next Materials, 12, 102004. DOI: 10.1016/j.nxmate.2026.102004
  19. Wang, C., Jin, G., Wang, W., Zhao, C., Wang, S., Zhao, Y., Ni, J. (2026). Nanomaterials Driving Technological Advancements in Enhanced Oil Recovery from Low-Permeability Tight Oil Reservoirs: Opportunities and Challenges. Nanomaterials, 16(8), 464. DOI: 10.3390/nano16080464
  20. Peng, Y., Han, F., Zhao, Y., Wang, H., Gong, J., Wu, K. (2025). Research on wettability and interaction mechanism of silica nanoparticles on coal surface: Based on experiments and molecular dynamics simulations. Appl. Surf. Sci., 713, 164266, Dec. 2025, DOI: 10.1016/j.apsusc.2025.164266
  21. Matarneh, S., El-Rayyes, A., Bahl, A., Sathish, T., Kavisri, M., Moovendhan, M. (2026). Silica nanoparticle-induced modulation of oil–water interfacial dynamics for enhanced oil recovery. Surfaces and Interfaces, 96, 109829, Sep. 2026. DOI: 10.1016/j.surfin.2026.109829
  22. Vaganov, R.A., Zhigarev, V.A., Pryazhnikov, M.I., Shebeleva, A.A., Nemtsev, I.V., Minakov, A.V. (2026). Improving the efficiency of surfactant and polymer solutions by modifying them with nanoparticle additives to increase oil recovery. Chem. Eng. Sci., 321, 122732. DOI: 10.1016/j.ces.2025.122732
  23. Xu, X., Meng, C., Zhan, J., Wang, Q., Zhang, M., Wang, C., Pan, J., Cui, H., Zhao, X. (2026). Nanoparticle-plant interactions: Uptake, transport, physiological effects, and environmental implications. Journal of Hazardous Materials Advances, 22, 101123. DOI: 10.1016/j.hazadv.2026.101123
  24. Bendaoued, A., Messaoud, M., Harzallah, O., Bistac, S., Salhi, R. (2022). Nano-TiO2 effect on thermal, rheological and structural properties of thermoplastic polypropylene nanocomposites. Journal of Materials Research and Technology, 17, 2313–2325, Mar. 2022, DOI: 10.1016/j.jmrt.2022.01.114
  25. Haruna, M.A., Tangparitkul, S., Wen, D. (2024). Dispersion of polyacrylamide and graphene oxide nano-sheets for enhanced oil recovery. Colloids Surf. A Physicochem. Eng. Asp., 699, 134689, DOI: 10.1016/j.colsurfa.2024.134689
  26. Djouonkep, L.D.W., Xie, B., Tao, H., Chen, J., Zhuo, L., Selabi, N.B.S., Zhao, L. (2024). Enhanced amphoteric polymer filtration reducer with vinyl-functionalized nanosilica for high-salt and ultra-high temperature water-based drilling environments. Geoenergy Science and Engineering, 236, 212743. DOI: 10.1016/j.geoen.2024.212743
  27. Khedulkar, A.P., Bobade, R.G., Doong, R., Pandit, B., Ky, N.M., Ambare, R., Hoang, TD., Kumar, K.J. (2025). Bio-based nanomaterials as effective, friendly solutions and their applications for protecting water, soil, and air. Mater. Today Chem., 46, 102688. DOI: 10.1016/j.mtchem.2025.102688
  28. Nyah, F., Ridzuan, N., Aziz. M.A.B.A., Gbonhinbor, J.R., Money, B., Nwaichi, P.I., Umunnawuike, C., Abutu, D., Agi, A. (2025). Bibliometric Insights into Cellulose Nanoparticles: Advancing Sustainable Enhanced Oil Recovery in HTHP Reservoirs. SPE Nigeria Annual International Conference and Exhibition, SPE, Aug. 2025. DOI: 10.2118/228643-MS
  29. Suliman, Z.A., Ibrahim, A.A., Mecha, C.A., Chollom, M.N. (2025). Photocatalytic degradation and antibacterial efficacy of novel synthesized green Cu–Fe metal organic framework derived from Acacia nilotica extract. Discover Chemistry, 2(1), 219. DOI: 10.1007/s44371-025-00297-7
  30. Nguyen, T.T.H., Nyugen, X.C., Nguyen, D.L.T., Nguyen, D.D., Vo, T.Y.B., Vo, Q.N., Nguyen, T.D., Ly, Q.V., Ngo, H.H., Vo, D.-V.H., Nguyen, T.P., Kim, I.T., Le, Q.V., (2023). Converting biomass of agrowastes and invasive plant into alternative materials for water remediation. Biomass Convers. Biorefin., 13(6), 5391–5406. DOI: 10.1007/s13399-021-01526-6
  31. Mary, P.P., Kumaresavanji, M., Venkatesh, P.S., Kannan, N., Ragupathy, P., Vasumathi, V. (2026). Upcycling Acacia auriculiformis leaf waste into Eco- Graphite: A sustainable route to high-performance rGO-MoO3 photocatalysts. Emergent Mater., 9(1–3), 34. DOI: 10.1007/s42247-026-01362-2
  32. Chavda, V., Borah, P., Thakur, M., Patil, Y., Bhargawa, B., Gandhi, M., Lee, Y-S., Ghotekar, S., Jain, P., Raghav, S., Yadav, A. K., Kim, W., Ahmaruzzaman, Md., (2026). Deep eutectic solvent engineered metal–organic frameworks (DES-MOFs): A green pathway toward next-gen advanced functional materials. Chemical Engineering Journal, 545, 179356. DOI: 10.1016/j.cej.2026.179356
  33. Mgxadeni, N., Kabane, B., Bahadur, I., Varma, R.S., Singh, S.K. (2023). Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent update. Journal of Ionic Liquids, 3(2), 100065. DOI: 10.1016/j.jil.2023.100065
  34. Jiang, S., Zeng, Y., Zhang, Y., He, Y.-C. (2026). Selective fractionation and enhanced cellulose accessibility of corn Stover using a cetyltrimethylammonium bromide/ethylene glycol/tartaric acid ternary deep eutectic solvent. Int. J. Biol. Macromol., 154045. DOI: 10.1016/j.ijbiomac.2026.154045
  35. Sanjeeta, Singh, A., Kavirajwar, J. (2025) Dynamic properties and diverse applications of deep eutectic solvents, Journal of Ionic Liquids, 5(1), 100135, Jun. 2025, DOI: 10.1016/j.jil.2025.100135
  36. Zhu, D., Yin, J., Han, S., Zhang, R., Dai, C., He, J., Li, H., Zhu, W., Li, H., Jiang, W, (2026). Ion−dipole−induced high stability of acidic DESs for efficient extractive and oxidative desulfurization. Chemical Engineering Journal, 530, 173485. DOI: 10.1016/j.cej.2026.173485
  37. Shao, Y., Liu, H., Li, L., Wang, K., Wang, X. (2025). Effect and mechanism of hydrogen bonding on the shape-memory effect of wood hydrothermal response. Ind. Crops Prod., 230, 121115, Aug. 2025, DOI: 10.1016/j.indcrop.2025.121115
  38. Suopajärvi, T., Sirviö, J.A., Liimatainen, H. (2017). Nanofibrillation of deep eutectic solvent-treated paper and board cellulose pulps. Carbohydr. Polym., 169, 167–175. DOI: 10.1016/j.carbpol.2017.04.009
  39. Putranto, A.W., Dutta, S., Priananda, W., Illias, H.A., Syafiqoh, Q., Masruchin, N., Wibisono, Y., Suhartini, S., Chua, A.S.M., Ngoh, G,C., (2025). Enhancement of cellulose nanocrystal yield from oil palm empty fruit bunches: A comparative study of binary and ternary deep eutectic solvents with pulsed electric field pretreatment. Biomass Bioenergy, 196, 107672. DOI: 10.1016/j.biombioe.2025.107672
  40. Abbas, A. H., Serikov, G., Zhuniskenov, Y., Serikkali, Nyah, F., Ridzuan, N., Gbonhinbor, J., Agi, A. (2024). Revisiting Troubleshooted Drill Stem Test: Methodological Framework Incorporating Artificial Intelligence. SPE Nigeria Annual International Conference and Exhibition, SPE, Aug. 2024. DOI: 10.2118/221608-MS
  41. Husein, N., Ismail, I., Mani, S.V.S., Ker, W.Z., Boyou, N.V., Ismail, A.S.I., Sulaiman, W.R.W. (2020). Experimental investigation of gas-brine liquid flow in horizontal pipeline. SN Appl. Sci., 2(12), 2184. DOI: 10.1007/s42452-020-03944-z
  42. Hadjer, D., Larbi, H., Abdelkrim, L. (2024). Effect of Xanthan gum on rheological properties of water - crude oil emulsions. Brazilian Journal of Technology, 7(4), e76330. DOI: 10.38152/bjtv7n4-050
  43. Bader, Q.A., Al-Sharify, Z., Dhabab, J.M., Zaidan, H.K., Rheima, A.M., Athair, D.M., Joseph, T.M., Kianfar, E., (2024). Cellulose nanomaterials in oil and gas industry and bio-manufacture: Current situation and future outlook. Case Studies in Chemical and Environmental Engineering, 10, 100993. DOI: 10.1016/j.cscee.2024.100993
  44. Sharma, V., Wang, J. X., Tsai, M-L., Yadav, A., Dong, C-D., Nargotra, P., Sun, P-P. (2025). Bioprocessing of pineapple leaf waste biomass using an integrated ultrasound-deep eutectic solvent pretreatment approach for improved bioethanol production. J. Biotechnol., 404, 83–93. DOI: 10.1016/j.jbiotec.2025.04.011
  45. Rodriguez-Quiroz, E.S., Olivares-Xometl, O., Santacruz-Vázquez, V., Santacruz-Vázquez, C., Arellanes-Lozada, P., Rubio-Rosas, E. (2023) Production of Cellulosic Microfibers from Coffee Pulp via Alkaline Treatment, Bleaching and Acid Hydrolysis, Materials, 16(24), 7607, Dec. 2023, DOI: 10.3390/ma16247607
  46. Abutu, D., Yussof, H.W., Nwaichi, P.I., Umunnawuike, C., Nyah, F., Money, B., Agi, A. (2025). Biohydrogen production and storage from depleted hydrocarbon reservoirs: A review of the strategies to improve biohydrogen production for sustainable energy transition. Next Energy, 9, 100458. DOI: 10.1016/j.nxener.2025.100458
  47. Nyah, F., Ridzuan, N., Epelle. E., Aziz. M. A. B. A., Gbonhinbor, J. R., Money, B., Abutu, D., Agi, A. (2026). Cellulose bionanomaterial design for enhanced oil recovery: A review of existing, emerging technologies and future outlook. Petroleum Research, 11(2), 641–686. DOI: 10.1016/j.ptlrs.2025.12.002
  48. Kumar, K.R., Vishnu, N.G.C.S., Uppuluri, K.B., Selvasembian, R. (2025). Integrated formic acid and deep eutectic solvent mediated sustainable synthesis of cellulose nanocrystals from Sterculia foetida shells, Prep. Biochem. Biotechnol., 55(4), 403–416. DOI: 10.1080/10826068.2024.2419873
  49. Prasetyaningsih, Y., Kusumastuti, Y., Ariyanto, T., Hidayat, M. (2025). Optimization of cellulose yield from oil palm trunks with deep eutectic solvents using response surface methodology. Green Processing and Synthesis, 14(1). DOI: 10.1515/gps-2024-0252
  50. Rutkaite, R., Bendoraitiene, J., Pavuolyte, G., Peciulyte, L., Liudvinaviciute, D., Barvainis, P., Varzinskas, V., (2026). Hemp Seed Hull and Cellulose Acetate Thermoplastic Biocomposites and Their Properties. Molecules, 31(9), 1453. DOI: 10.3390/molecules31091453
  51. Wu, X., Yuan, X., Zhao, J., Ji, D., Guo, H., Yao, W., Li, X., Zhang, L., (2023). Study on the effects of different pectinase/cellulase ratios and pretreatment times on the preparation of nanocellulose by ultrasound-assisted bio-enzyme heat treatment. RSC Adv., 13(8), 5149–5157. DOI: 10.1039/D2RA08172E
  52. Rasheed, M., Jawaid, M., Parveez, B., Zuriyati, A., Khan, A. (2020). Morphological, chemical and thermal analysis of cellulose nanocrystals extracted from bamboo fibre. Int. J. Biol. Macromol., 160, 183–191. DOI: 10.1016/j.ijbiomac.2020.05.170
  53. Wang, T., Jiang, Y., Shen, R., Shen, F., Tian, D. (2025). Deep Eutectic Solvents Lignin: Extraction. Handbook of Lignin, Singapore: Springer Nature Singapore, pp. 1–21. DOI: 10.1007/978-981-97-2664-6_67-1
  54. Li, P., Yang, C., Jiang, Z., Jin, Y., Wu, W. (2023). Lignocellulose pretreatment by deep eutectic solvents and related technologies: A review. Journal of Bioresources and Bioproducts, 8(1), 33–44. DOI: 10.1016/j.jobab.2022.11.004
  55. Stanciu, M.-C., Tanasă, F., Teacă, C.-A. (2025). Crystallinity Changes in Modified Cellulose Substrates Evidenced by Spectral and X-Ray Diffraction Data. Polysaccharides, 6(2), 30. DOI: 10.3390/polysaccharides6020030
  56. Pinto, T.C., Barba, L., Papadogiannakis, C., Garcia, A.K., Caliandro, R., Sabet, S., Valoppi, F. (2026). Unveiling the fate of lipid crystalline structures in engineered emulsions during in vitro digestion. Food Chem., 513, 149077. DOI: 10.1016/j.foodchem.2026.149077
  57. Nugroho, R.W.N., Tardy, B.L., Eldin, S.M., Ilyas, R.A., Mahardika, M., Masruchin, N. (2023). Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals. Ultrason. Sonochem., 99, 106581. DOI: 10.1016/j.ultsonch.2023.106581
  58. Zhu, P., Feng, L., Ding, Z., Bai, X. (2022). Preparation of Spherical Cellulose Nanocrystals from Microcrystalline Cellulose by Mixed Acid Hydrolysis with Different Pretreatment Routes. Int. J. Mol. Sci., 23(18), 10764. DOI: 10.3390/ijms231810764
  59. Hardiningtyas, S.D., Putra, B.U., Angarra, K.B., Yuniasani, I., Ramadhan, W., Pari, R.F., Uji, Hastuti, N., Indrawan, D.A., Wakabayashi, R., Goto, M., Kamiya, N., (2024). Sustainable Synthesis of Cellulose Nanofibers from Industrial Agar Seaweed Waste Biomass Using Hydrated Deep Eutectic Solvents. Waste Biomass Valorization, 15(8), 4899–4913. DOI: 10.1007/s12649-024-02499-z
  60. Imiete, I.E., Giannini, L., Tadiello, L., Orlandi, M., Zoia, L. (2023). The effect of sulfate half-ester groups on the mechanical performance of cellulose nanocrystal-natural rubber composites. Cellulose, 30(14), 8929–8940. DOI: 10.1007/s10570-023-05432-0
  61. Yin, L., Zhang, S., Zhao, D., Wang, R., Jin, Z., Xu, H. (2026). Deep eutectic solvent-ultrasound synergy for simultaneous extraction-modification of Pyrus pyrifolia peel pectin and cellulose nanocrystals: multifaceted physicochemical and structural characterization. J. Food Sci. Technol. DOI: 10.1007/s13197-025-06505-7
  62. Yeo, C.-E., Sung, H.-J. (2025). Eco-Friendly Production of Lignin-Containing Cellulose Nanofibers from Sugarcane Bagasse Fines via Sequential Thermal Hydrolysis–Deep Eutectic Solvents Pretreatment. Polymers (Basel), 18(1), 85. DOI: 10.3390/polym18010085
  63. Jančíková, V., Jablonský, M., Szadkowska, D., Szadkowski, J., Gemeiner, P. (2024). DES-like mixtures based on choline chloride and lactic acid for fractionation of hemp fibers. Journal of Ionic Liquids, 4(1), 100091. DOI: 10.1016/j.jil.2024.100091
  64. Lopez-Miranda, J.L., Elizalde-Mata, A., Esparza, R., Estevez, M. (2025). Study of Sargassum spp. as a biosorbent material for the elimination of contaminants dissolved in water. MRS Adv., 10(3), 379–385. DOI: 10.1557/s43580-025-01169-z
  65. Meraj, A., Jawaid, M., Karim, Z., Fouad, H. (2025). Preparation of cellulose nanocrystals extracted from kenaf fiber with natural deep eutectic solvent. Biomass Convers. Biorefin., 15(18), 25351–25358. DOI: 10.1007/s13399-025-06850-9
  66. Rasoolzadeh, N., Nikzad, M., Mohammadi, M., Bakhshi, H., Amini, G., Koupaie, E.H. (2025). Optimization of cellulose nanocrystal isolation from sorghum bicolor stem using deep eutectic solvents: a response surface methodology approach. Biomass Convers. Biorefin., 5(10), 16189–16212. DOI: 10.1007/s13399-024-06410-7
  67. Zhang, H., Wu, R., Chen, X., Ni, S., Xu, C., Fu, Y., Qin, M., Zhang, Y., (2025). High-efficient fractionation of poplar chips by ternary deep eutectic solvents system for elevating enzymatic hydrolysis. Ind. Crops Prod., 225, 120489. DOI: 10.1016/j.indcrop.2025.120489
  68. Karimian, D., Anzuoni, V., Smania, Z., Orian, L., Gross, S., Carraro, M. (2025). Enhanced Nanocellulose Production from Cotton and Textile Waste Using Binary and Ternary Natural Deep Eutectic Solvents. Adv. Sustain. Syst., 9(1). DOI: 10.1002/adsu.202400525
  69. Yong, W.S., Yong, C.S.C., Yeu, Y.L., Thangavelu, S.K., Chai, A.B., Chung, P.P. (2026). Valorization of sago hampas: extraction of microcrystalline cellulose and its role in enhancing bio-composite properties. Cellulose, 33(5), 2857–2885, Mar. 2026, DOI: 10.1007/s10570-026-07010-6
  70. Zhang, J., Huo, H., Zhang, L., Yang, Y., Li, H., Ren, Y., Zhang, Z. (2022). Effect of High-Temperature Hydrothermal Treatment on the Cellulose Derived from the Buxus Plant. Polymers (Basel), 14(10), 2053. DOI: 10.3390/polym14102053
  71. Gabriel, T., Wondu, K., Dilebo, J. (2021). Valorization of khat (Catha edulis) waste for the production of cellulose fibers and nanocrystals. PLoS One, 16(2), e0246794. DOI: 10.1371/journal.pone.0246794
  72. Koistinen, A., Vuorinen, T., Maloney, T. (2025). The effect of alkaline pre-treatment on cellulose pulp fiber dissolution. Carbohydrate Polymer Technologies and Applications, 11, 100978. DOI: 10.1016/j.carpta.2025.100978
  73. Nyah, F., Ridzuan, N., Aziz, M.A.B.A., Gbonhinbor, J.R., Nwaichi, P.I., Umunnawuike, C., Abutu, D., Agi, A. (2026). Deep Eutectic Solvents-Derived Functionalized Cellulose Nanoparticles for Interfacial and Wettability Control in Enhanced Oil Recovery. SPE Nigeria Annual International Conference and Exhibition, SPE, Aug. 2026. DOI: 10.2118/234812-MS
  74. Ramli, N.A.N., Sam, S.T., Yaakub, A.R.W., Abdullah, M.F. (2024). Isolation of Cellulose Nanocrystals from Rice Husk using Natural Deep Eutectic Solvent, International Journal of Biomass Utilization and Sustainable Energy (IJBUSE), 1, Sep. 2024, DOI: 10.58915/ijbuse.v1.2024.1081
  75. Rasoolzadeh, N., Nikzad, M., Mohammadi, M., Bakhshi, H., Amini, G., Koupaie, E.H. (2025). Optimization of cellulose nanocrystal isolation from sorghum bicolor stem using deep eutectic solvents: a response surface methodology approach. Biomass Convers. Biorefin., 15(10), 16189–16212. DOI: 10.1007/s13399-024-06410-7
  76. Beyan, S.M., Amibo, T.A., Prabhu, S.V., Ayalew, A.G. (2021). Production of Nanocellulose Crystal Derived from Enset Fiber Using Acid Hydrolysis Coupled with Ultrasonication, Isolation, Statistical Modeling, Optimization, and Characterizations. J. Nanomater., 2021, 1–12. DOI: 10.1155/2021/7492532
  77. Li, J., Wang, Z., Wang, P., Tian, J., Liu, T., Guo, J., Zhu, W., Khan, M.R., Xiao, H., Song, J. (2024). On rheological properties of disc-shaped cellulose nanocrystals. Carbohydr. Polym., 330, 121764. DOI: 10.1016/j.carbpol.2023.121764
  78. Nyah, F., Ridzuan, N., Aziz. M.A.B.A., Gbonhinbor, J.R., Money, B., Nwaichi, P.I., Umunnawuike, C., Abutu, D., Agi, A. (2025) Cutting-Edge Strategies for Flow Assurance and Multiphase Flow Management in Modern Oil and Gas Operations. SPE Nigeria Annual International Conference and Exhibition, SPE. Aug. 2025. DOI: 10.2118/228644-MS
  79. Rana, A.K., Thakur, M.K., Gupta, V.K., Thakur, V.K. (2024). Exploring the role of nanocellulose as potential sustainable material for enhanced oil recovery: New paradigm for a circular economy. Process Safety and Environmental Protection, 183, 1198–1222. DOI: 10.1016/j.psep.2024.01.085
  80. Money, B., Modather, R.H., Abutu, D., Ismail, N., Agi, A., Nyah, F., Mahat, S.Q.A. (2025). A review on advancing clay-based geopolymers for high-temperature oil well cements: Mechanisms, durability, and applications. Petroleum Research. DOI: 10.1016/j.ptlrs.2025.08.005
  81. Moud, A.A. (2023). CNC Gel Rheology Meets Mechanical Characteristics, in Advances in Rheology of Materials, IntechOpen, 2023. DOI: 10.5772/intechopen.106231
  82. Tatli, B., Rousseau, A.R., Xing, W., Hirsch, M., Cranston, E.D., Abitbol, T. (2026). From Brittle to Flexible: Influence of Glucose‐Based Additives on Cellulose Nanocrystal Self‐Assembly in Suspension and Dried Photonic Films. Adv. Opt. Mater., 14(6). DOI: 10.1002/adom.202503120
  83. Pinto, E.A., Dávila, J.L., d’Ávila, M.A. (2019). Rheological studies on nanocrystalline cellulose/alginate suspensions. J. Mol. Liq., 277, 418–423, Mar. 2019, DOI: 10.1016/j.molliq.2018.12.091
  84. Money, B., Mahat, S.Q.A.B., Melia, A., Gbadamosi, A., Oseh, J., Junin, r., Modather, R.H., Umunnawuike, C., Nyah, F., David, A., Nwaichi, P.I, Agi, A. (2025). Appraising the Impact of Activated Clay Geopolymer as a Sustainable Geopolymer Cement for Oilwell Applications. SPE Nigeria Annual International Conference and Exhibition, SPE, Aug. 2025. DOI: 10.2118/228642-MS
  85. Nwaichi, P.I., Ridzuan, N., Nwaichi, E.O., Umunnawuike, C., Abutu, D., Nyah, F., Money, B., Agi, A. (2025). Advances in oilwell cement retarders: a bibliometric and systematic review of mechanisms, challenges, emerging trends, and future directions. Discover Concrete and Cement, 1(1), 8. DOI: 10.1007/s44416-025-00008-6
  86. Abbas, A.H., Serikov, G., Zhuniskenov, Y., Serikkali, Nyah, F., Ridzuan, N., Gbonhinbor, J., Agi, A. (2024). Navigating the Future: A Numerical Study of Natural Polymers and CO2 in Offshore Applications. SPE Nigeria Annual International Conference and Exhibition, SPE, Aug. 2024. DOI: 10.2118/221614-MS
  87. You, L., Marcolini, B., Bour, J., Grysan, P., Fleming, Y., Fischer, P., Soukoulis, C., (2025). Physicochemical, morphological, and rheological properties of cellulose nanofibrils produced via ultra-high-pressure homogenization. Carbohydrate Polymer Technologies and Applications, 9, 100635. DOI: 10.1016/j.carpta.2024.100635
  88. Wenhao, Z. (2021). Influence of Temperature and Concentration on Viscosity of Complex Fluids, J. Phys. Conf. Ser., 1965(1), 012064. DOI: 10.1088/1742-6596/1965/1/012064
  89. Altay, B. N., Aksoy, B., Atkinson, J., Lewis, C. L., Diaz-Acosta, C., Francis, R. (2025). Flow dynamics of agricultural waste nanofibers: shear, temperature, and oscillatory insights. Cellulose, 32(5), 3077–3094. DOI: 10.1007/s10570-025-06444-8
  90. Shim, Y.H., Kong, T.Y., Kim, S.Y. (2025). Reversible Control of Rheological Properties in Microgel Composites via Nanoparticle Aggregation. ACS Appl. Mater. Interfaces, 17(27), 39616–39627. DOI: 10.1021/acsami.5c06287
  91. Zhao, Y., Zhang, F., Chen, M., Liu, F., Zheng, B., Miao, W., Gao, H., Zhou, R. (2024). Cellulose nanofibrils-stabilized food-grade Pickering emulsions: Clarifying surface charge’s contribution and advancing stabilization mechanism understanding. Food Hydrocoll., 152, 109920. DOI: 10.1016/j.foodhyd.2024.109920
  92. Liu, E., Meng, H., Zhang, H., Liang, H., Wu, Z. (2024). Nanocellulose, a Renewable Biobased Functional/Reinforcement Additive for Composite Coating Materials: A Review. ACS Appl. Polym. Mater., 6(1), 28–48. DOI: 10.1021/acsapm.3c02088
  93. Fahma, F., Febiyanti, I., Lisdayana, N., Arnata, I.W., Sartika, D. (2021). Nanocellulose as a new sustainable material for various applications: a review. Archives of Materials Science and Engineering, 2(109), 49–64. DOI: 10.5604/01.3001.0015.2624
  94. Zhang, Q., Ding, Z., Wang, X., Huang, J. (2026). Unveiling Nanocellulose from the Perspective of Morphological Engineering. Molecules, 31(16), 2743. DOI: 10.3390/molecules31162743
  95. Abutu, D., Aderemi, B.O., Ameh, A.O., Yussof, H.W., Gbonhinbor, J., Money, B., Nyah, F., Umunnawuike, C., Nwaichi, P.I., Agi, A. (2025). Optimization of Ethanol Fermentation in a Bubble Column Bioreactor Using Response Surface Methodology with Ferric Oxide Nanoparticle-Modified Supports. SPE Nigeria Annual International Conference and Exhibition, SPE, Aug. 2025. DOI: 10.2118/228638-MS
  96. Muhammed, A.A., Omotosho, Y.A., Aliu, H.O., Adeleke, A.T. (2026). Interfacial tension reduction at crude oil contact with brine-based alumina nanofluid: Experimental and statistical evaluation. Progress in Engineering Science, 3(1), 100247. DOI: 10.1016/j.pes.2026.100247
  97. Deng, X., Patil, S., Al Shehri, D., Kamal, M.S., Shakil, S.M., Zhou, X., Mahmoud, M., Al Shalabi, E.W., Hassan, A. (2023). IFT Reduction Negatively Impacts Oil Recovery When Wettability Alteration Happens. Gas & Oil Technology Showcase and Conference, SPE, Mar. 2023. DOI: 10.2118/214178-MS
  98. Pinto, N O.F., Bourbon, A.I., Martins, D., Pereira, A., Cerqueira, M.A., Pastrana, L., Gama, M., Azeredo, H.M.C., Rosa, M.F. (2024). Bacterial cellulose nanocrystals or nanofibrils as Pickering stabilizers in low-oil emulsions: A comparative study. Food Hydrocoll., 157, 110427, Dec. 2024, DOI: 10.1016/j.foodhyd.2024.110427
  99. Hansini, A.M.P., Galpaya, G.D.C.P., Gunasena, M.D.K.M., Abeysundara, P.M., Kirthika, V., Bhagya, L., Gunawardana, H.D.C.N., Koswattage, K.R. (2025). From Nature to Innovation: Advances in Nanocellulose Extraction and Its Multifunctional Applications. Molecules, 30(13), 2670. DOI: 10.3390/molecules30132670
  100. Dubey, S., Majumder, S.K. (2026). Synergistic Application of a Plant-Derived Surfactant and CO2 Foam for Enhanced Oil Recovery: Linking Interfacial Phenomena to Core-Scale Performance. Energy & Fuels, 40(21), 11397–11418, May 2026, DOI: 10.1021/acs.energyfuels.6c00630
  101. Wang, C., Jin, G., Wang, W., Zhao, C., Wang, S., Zhao, Y., Ni, J. (2026). Nanomaterials Driving Technological Advancements in Enhanced Oil Recovery from Low-Permeability Tight Oil Reservoirs: Opportunities and Challenges. Nanomaterials, 16(8), 464. DOI: 10.3390/nano16080464
  102. Ebrahimi, M., Ghalenavi, H., Schaffie, M., Ranjbar, M., Hemmati-Sarapardeh, A. (2025). Experimental investigation of wettability alteration in sandstone rock by nanoparticles, gelatin biopolymer, salt ions, and synthesized Fe3O4/gelatin nanocomposite for EOR applications. Sci. Rep., 15(1), 33260. DOI: 10.1038/s41598-025-18591-w
  103. Mumbere, W., Sagala, F., Gupta, U., Bbosa, D. (2025). Reservoir Potential Unlocked: Synergies Between Low-Salinity Water Flooding, Nanoparticles and Surfactants in Enhanced Oil Recovery─A Review. ACS Omega, 10(29), 31216–31261. DOI: 10.1021/acsomega.5c02533
  104. Al-Musawi, S., Rashidi, F., Amjad-Iranagh, S. (2025). Novel insights into electrical double layers in carbonate reservoirs under low-salinity water injection using molecular dynamics simulation. Sci. Rep., 15(1), 31061. DOI: 10.1038/s41598-025-14647-z
  105. Song, C., Jang, H., Lee, J. (2023). Synthesis and dispersion stability of seawater-based nano-smart water for application in high-temperature and high-salinity conditions. Colloids Surf. A Physicochem. Eng. Asp., 674, 131910. DOI: 10.1016/j.colsurfa.2023.131910
  106. Maiki, E.P., Sun, R., Ren, S., AlRassas, A.M., Huang, Y. (2023). Investigating the low salinity effect in a sandstone reservoir through electro-kinetic potential analysis. Chem. Phys., 574, 112028. DOI: 10.1016/j.chemphys.2023.112028
  107. Nyah, F., Ridzuan, N., Nwaichi, P.I., Umunnawuike, C., Agi, A. (2024). Comprehensive review on the role of salinity on oil recovery mechanisms during chemical flooding. J. Mol. Liq., 415, 126308. DOI: 10.1016/j.molliq.2024.126308
  108. Abutu, D., Yussof, H.W., Nwaichi, P.I., Umunnawuike, C., Nyah, F., Money, B., Agi, A. (2026). Utilizing depleted oil reservoirs for in-situ biohydrogen production: addressing knowledge gaps, sustainable pathways and future research directions. Fuel, 406, 136710. DOI: 10.1016/j.fuel.2025.136710
  109. Ke, C., Yuan, B., Li, Y., Zhang, W., Tian, J., Dai, C. (2024). Wettability Alteration Induced by Nanoparticle Nonuniform Adsorption and its Impact on Water–Oil Relative Permeability in Heterogeneous Porous Media. Energy & Fuels, 38(17), 16133–16148. DOI: 10.1021/acs.energyfuels.4c02944
  110. Mondal, M.C., Uddin, H.M.W., Progoti, Q. R.M., Tushar, M.A.-N., Dutta, A., Saif, T., Malitha, S.B. (2026). Enhanced oil recovery via metal oxide nanoparticles: A review of recent advancements, core mechanisms, and future outlook. Next Materials, 12, 102004, Jul. 2026, DOI: 10.1016/j.nxmate.2026.102004
  111. Tangparitkul, S., Sukee, A., Jiang, J., Harbottle, D. (2024). Crude oil displacement enhanced by interfacially active nanoparticles and their coupling effect with low-salinity brines. J. Mol. Liq., 408, 125362. DOI: 10.1016/j.molliq.2024.125362
  112. Manimaran, M., Norizan, M.N., Kassim, M.H.M., Adam, M.R., Abdullah, N., Norrrahim, M.N.F. (2025). Critical review on the stability and thermal conductivity of water-based hybrid nanofluids for heat transfer applications. RSC Adv., 15(18), 14088–14125. DOI: 10.1039/D5RA00844A
  113. Nyah, F., Ridzuan, N., Aziz. M.A.B.A., Gbonhinbor, J.R., Nwaichi, P.I., Umunnawuike, C., Abutu, D., Agi, A. (2026). Evaluation of Cellulose Nanoparticles Synthesized from Paper Waste as High-Temperature, High-Salinity Nanofluid Agents for Enhanced Oil Recovery. SPE Nigeria Annual International Conference and Exhibition, SPE. DOI: 10.2118/234813-MS
  114. Abutu, D., Nwaichi, P.I., Umunnawuike, C., Nyah, F., Money, B., Yussof, H.W., Agi, A. (2025). Numerical simulation of microbial biohydrogen production under high-pressure, high-temperature conditions for enhanced recovery from depleted reservoirs. Petroleum Research. 11(1), 206–216. DOI: 10.1016/j.ptlrs.2025.07.006
  115. Kandiel, Y.E., Attia, G.M., Metwalli, F.I., Khalaf, R.E., Mahmoud, O. (2025). Nanoparticles in enhanced oil recovery: state-of-the-art review. J. Pet. Explor. Prod. Technol., 15(4), 66. DOI: 10.1007/s13202-025-01965-1
  116. Khormali, A., Ahmadi, S. (2026). Hybrid nano-chemical enhanced oil recovery processes in oil reservoirs: A critical review. Results in Engineering, 32, 112077. DOI: 10.1016/j.rineng.2026.112077

Last update:

No citation recorded.

Last update:

No citation recorded.