DOI: https://doi.org/10.9767/jcerp.20762

The Application of Transition Metal Nitride Catalyst in the HDO Reaction of Lignin and Its Model Compounds

Department of Chemical Engineering, Hamhung Branch of Science University, Prof. Jong Nam, Hamhung, DPRK 99903, North Korea

Received: 5 Jun 2026; Revised: 8 Jun 2026; Accepted: 22 Jun 2026; Available online: 9 Jul 2026; Published: 30 Dec 2026.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2026 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
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Abstract

As the only abundant and renewable non-fossil resource that provides aromatic compounds in nature, lignin is an important raw material for the production of new energy and high-value chemicals. Transition metal nitride is widely used as a good hydrodeoxygenation (HDO) catalyst in the catalytic conversion reaction of lignin and its model compounds thanks to its crystal structure and properties, and good hydrodeoxygenation activity similar to noble metals. This paper reviewed the application of transition metal nitride catalysts in catalytic conversion of lignin and its model compounds. And the paper comprehensively analyzed the components of transition metal nitride catalyst, the nitriding method and the molar hourly space velocities (MHSV) in the preparation process, the carrier, the addition of other metals, the influence of reaction conditions on the catalytic activity and the reaction mechanism. In addition, the paper discussed the problems arising in applying the transition metal nitride catalysts in the reaction of lignin and its model compound HDO were proposed, and proposed the ways to develop nitride catalysts with higher catalytic performance and wider application prospect. Copyright © 2026 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Keywords: Transition Metal Nitride; lignin; Hydrodeoxigenation; HDO; catalytic degradation; aromatic compound

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Section: Review Articles
Language : EN
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  1. Musa, S.D., Zhonghuab, T., Ibrahim, A.O., Habib, M. (2018). China's energy status: A critical look at fossils and renewable options. Renewable and Sustainable Energy Reviews, 81, 2281–2290. DOI: 10.1016/j.rser.2017.06.036
  2. Li, X., Luo, X., Jinb, Y., Li, J., Zhang, H., Zhang, A., Xie, J. (2018). Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels. Renewable and Sustainable Energy Reviews, 82, 3762–3797. DOI: 10.1016/j.rser.2017.10.091
  3. Dhyani, V., Bhaskar, T. (2018). A comprehensive review on the pyrolysis of lignocellulosic biomass. Renewable Energy, 129, 695-716. DOI: 10.1016/j.renene.2017.04.035
  4. Bohre, A., Dutta, S., Saha, B., Abu-Omar, M.M. (2015). Upgrading Furfurals to Drop-in Biofuels: An Overview. ACS Sustainable Chem. Eng., 3, 1263−1277. DOI: 10.1021/acssuschemeng.5b00271
  5. Li, H., Fang, Z., Smith Jr., R.L., Yang, S. (2016). Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials. Progress in Energy and Combustion Science, 55, 98–194. DOI: 10.1016/j.pecs.2016.04.004
  6. Saidi, M., Samimi, F., Karimipourfard, D., Nimmanwudipong, T., Gates, B.C., Rahimpour, M.R. (2014). Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation. Energy Environ. Sci., 7, 103–129. DOI: 10.1039/C3EE43081B
  7. Tribot, A., Amer, G., Alio, M.A., de Baynast, H., Delattre, C., Pons, A., Mathias, J.-D., Callois, J.-M., Vial, C., Michaud, P., Dussap, C.-G. (2019). Wood-lignin: Supply, extraction processes and use as bio-based material. European Polymer Journal, 112, 228–240. DOI: 10.1016/j.eurpolymj.2019.01.007
  8. Ji, N., Song, J., Diao, X., Song, C., Liu, Q., Zheng, M. (2017). Transformation of Lignin and Its Model Compounds into Value-Added Chemicals Using Sulfide Catalysts. Progress in Chemistry, 29, 563-578. DOI: 10.7536/PC161103
  9. Yao, L., Wei, X., Zong, Z., Lu, Y., Zhao, W., Cao, J. (2013). Structural Investigation and Application of Lignins. Progress in Chemistry, 25, 838-858. DOI: 10.7536/PC121023
  10. Agarwal, A., Rana, M., Park, J.-H. (2018). Advancement in technologies for the depolymerization of lignin. Fuel Processing Technology, 181, 115–132. DOI: 10.1016/j.fuproc.2018.09.017
  11. Wang, H., Pu, Y., Ragauskas, A., Yang, B. (2019). From lignin to valuable products--strategies, challenges, and prospects. Bioresource Technology, 271, 449–461. DOI: 10.1016/j.biortech.2018.09.072
  12. Mei, Q., Shen, X., Liu, H., Han, B. (2019). Selectively transform lignin into value-added chemicals. Chinese Chemical Letters, 30, 15–24. DOI: 10.1016/j.cclet.2018.04.032
  13. Jin, W., Pastor-Pérez, L., Shen, D., Sepúlveda-Escribano, A., Gu, S., Ramirez Reina, T. (2019). Catalytic Upgrading of Biomass Model Compounds: Novel Approaches and Lessons Learnt from Traditional Hydrodeoxygenation – a Review. Chem. Cat. Chem, 11, 924–960. DOI: 10.1002/cctc.201801722
  14. Fan, L., Zhang, Y., Liu, S., Zhou, N., Chen, P., Cheng, Y., Addy, M., Lu, Q., Omar, M.M., Liu, Y., Wang, Y., Dai, L., Anderson, E., Peng, P., Lei, H., Ruan, R. (2017). Bio-oil from fast pyrolysis of lignin: Effects of process and upgrading parameters. Bioresource Technology, 241, 1118–1126. DOI: 10.1016/j.biortech.2017.05.129
  15. Resasco, D.E. (2011). What Should We Demand from the Catalysts Responsible for Upgrading Biomass Pyrolysis Oil. J. Phys. Chem. Lett., 2, 2294–2295. DOI: 10.1021/jz201135x
  16. Furimsky, E. (2000). Catalytic hydrodeoxygenation. Applied Catalysis A: General, 199, 147–190. DOI: 10.1016/S0926-860X(99)00555-4
  17. Li, H., Riisager, A., Saravanamurugan, S., Pandey, A., Sangwan, R.S., Yang, S., Luque, R. (2018). Carbon-Increasing Catalytic Strategies for Upgrading Biomass into Energy-Intensive Fuels and Chemicals. ACS Catal., 8, 148−187. DOI: 10.1021/acscatal.7b02577
  18. Cheng, F., Brewer, C.E. (2017). Producing jet fuel from biomass lignin: Potential pathways to alkylbenzenes and cycloalkanes. Renewable and Sustainable Energy Reviews, 72, 673–722. DOI: 10.1016/j.rser.2017.01.030
  19. Feng, B., Kobayashi, H., Ohta, H., Fukuoka, A. (2014). Aqueous-phase hydrodeoxygenation of 4-propylphenol as a lignin model to n-propylbenzene over Re-Ni/ZrO2 catalysts. Journal of Molecular Catalysis A: Chemical, 388–389, 41–46. DOI: 10.1016/j.molcata.2013.09.025
  20. Funkenbusch, L.T., Mullins, M.E., Salam, M.A., Creaser, D., Olsson, L. (2019). Catalytic hydrotreatment of pyrolysis oil phenolic compounds over Pt/Al2O3 and Pd/C. Fuel, 243, 441–448. DOI: 10.1016/j.fuel.2019.01.139
  21. He, Y., Bie, Y., Lehtonen, J., Liu, R., Cai, J. (2019). Hydrodeoxygenation of guaiacol as a model compound of lignin-derived pyrolysis bio-oil over zirconia-supported Rh catalyst: Process optimization and reaction kinetics. Fuel, 239, 1015–1027. DOI: 10.1016/j.fuel.2018.11.103
  22. Bjelić, A., Grilc, M., Huš, M., Likozar, B. (2019). Hydrogenation and hydrodeoxygenation of aromatic lignin monomers over Cu/C, Ni/C, Pd/C, Pt/C, Rh/C and Ru/C catalysts: Mechanisms, reaction micro-kinetic modelling and quantitative structure-activity relationships. Chemical Engineering Journal, 359, 305–320. DOI: 10.1016/j.cej.2018.11.107
  23. Saidi, M., Rahzani, B., Rahimpour, M.R. (2017). Characterization and catalytic properties of molybdenum supported on nano gamma Al2O3 for upgrading of anisole model compound. Chemical Engineering Journal, 319, 143–154. DOI: 10.1016/j.cej.2017.02.149
  24. Ambursa, M.M., Sudarsanam, P., Voon, L.H., Abd Hamid, S.B., Bhargava, S.K. (2017). Bimetallic Cu-Ni catalysts supported on MCM-41 and Ti-MCM-41 porous materials for hydrodeoxygenation of lignin model compound into transportation fuels. Fuel Processing Technology, 162, 87–97. DOI: 10.1016/j.fuproc.2017.03.008
  25. Xu, C., Tang, S.-F., Sun, X., Sun, Y., Li, G., Qi, J., Li, X., Li, X. (2017). Investigation on the cleavage of β-O-4 linkage in dimeric lignin model compound over nickel catalysts supported on ZnO-Al2O3 composite oxides with varying Zn/Al ratios. Catalysis Today, 298, 89–98. DOI: 10.1016/j.cattod.2017.05.048
  26. Diao, X., Ji, N., Zheng, M., Liu, Q., Song, C., Huang, Y., Zhang, Q., Alemayehu, A., Zhang, L., Liang, C. (2018). MgFe hydrotalcites-derived layered structure iron molybdenum sulfide catalysts for eugenol hydrodeoxygenation to produce phenolic chemicals. Journal of Energy Chemistry, 27, 600–610. DOI: 10.1016/j.jechem.2017.07.008
  27. Song, W., Zhou, S., Hu, S., Lai, W., Lian, Y., Wang, J., Yang, W., Wang, M., Wang, P., Jiang, X. (2019). Surface Engineering of CoMoS Nanosulfide for Hydrodeoxygenation of Lignin-Derived Phenols to Arenes. ACS Catal., 9, 259−268. DOI: 10.1021/acscatal.8b03402.s001
  28. Wang, W., Tan, S., Wu, K., Zhu, G., Liu, Y., Tan, L., Huang, Y., Yang, Y. (2018). Hydrodeoxygenation of p-cresol as a model compound for bio-oil on MoS2: Effects of water and benzothiophene on the activity and structure of catalyst. Fuel, 214, 480–488. DOI: 10.1016/j.fuel.2017.11.067
  29. Ruiz, P.E., Frederick, B.G., De Sisto, W.J., Austin, R.N., Radovic, L.R., Leiva, K., García, R., Escalona, N., Wheeler, M.C. (2012). Guaiacol hydrodeoxygenation on MoS2 catalysts: Influence of activated carbon supports. Catalysis Communications, 27, 44–48. DOI: 10.1016/j.catcom.2012.06.021
  30. Berenguer, A., Bennett, J.A., Hunns, J., Moreno, I., Coronado, J.M., Lee, A.F., Pizarro, P., Wilson, K., Serrano, D.P. (2018). Catalytic hydrodeoxygenation of m-cresol over Ni2P/hierarchical ZSM-5. Catalysis Today, 304, 72–79. DOI: 10.1016/j.cattod.2017.08.032
  31. Hsu, P.-J., Lin, Y.-C. (2017). Hydrodeoxygenation of 4-methylguaiacol over silica-supported nickel phosphide catalysts: The particle size effect. Journal of the Taiwan Institute of Chemical Engineers, 79, 80–87. DOI: 10.1016/j.jtice.2017.02.020
  32. Korányi, T.I., Hensen, E.J.M. (2017). Preparative Aspects of Supported Ni2P Catalysts for Reductive Upgrading of Technical Lignin to Aromatics. Catal. Lett., 147, 1722–1731. DOI: 10.1007/s10562-017-2066-9
  33. Ghampson, I.T., Canales, R., Escalona, N. (2018). A study of the hydrodeoxygenation of anisole over Re-MoOx/TiO2 catalyst. Applied Catalysis A: General, 549, 225–236. DOI: 10.1016/j.apcata.2017.10.009
  34. Ranga, C., Lødeng, R., Alexiadis, V.I., Rajkhowa, T., Bjørkan, H., Chytil, S., Svenum, I.H., Walmsley, J., Detavernier, C., Poelman, H., Van Der Voort, P., Thybaut, J.W. (2018). Effect of composition and preparation of supported MoO3 catalysts for anisole hydrodeoxygenation. Chemical Engineering Journal, 335, 120–132. DOI: 10.1016/j.cej.2017.10.190
  35. Zhang, X., Tang, J., Zhang, Q., Liu, Q., Li, Y., Chen, L., Wang, C., Ma, L. (2019). Hydrodeoxygenation of lignin-derived phenolic compounds into aromatic hydrocarbons under low hydrogen pressure using molybdenum oxide as catalyst. Catalysis Today, 319, 41–47. DOI: 10.1016/j.cattod.2018.03.068
  36. Sirous-Rezaei, P., Jae, J., Ha, J.-M., Ko, C.H., Kim, J.M., Jeon, J.-K., Park, Y.-K. (2018). Mild hydrodeoxygenation of phenolic lignin model compounds over a FeReOx/ZrO2 catalyst: zirconia and rhenium oxide as efficient dehydration promoters. Green Chem., 20, 1472–1483. DOI: 10.1039/c7gc03823b
  37. Shetty, M., Murugappan, K., Green, W.H., Roman-Leshkov, Y. (2017). Structural Properties and Reactivity Trends of Molybdenum Oxide Catalysts Supported on Zirconia for the Hydrodeoxygenation of Anisole. ACS Sustainable Chem. Eng., 5, 5293−5301. DOI: 10.1021/acssuschemeng.7b00642.s001
  38. Liu, G.-H., Zong, Z.-M., Liu, Z.-Q., Liu, F.-J., Zhang, Y.-Y., Wei, X.-Y. (2018). Solvent-controlled selective hydrodeoxygenation of bio-derived guaiacol to arenes or phenols over a biochar supported Co-doped MoO2 catalyst. Fuel Processing Technology, 179, 114–123. DOI: 10.1016/j.fuproc.2018.05.035
  39. Ochoa, E., Torres, D., Moreira, R., Pinilla, J.L., Suelves, I. (2018). Carbon nanofiber supported Mo2C catalysts for hydrodeoxygenation of guaiacol: The importance of the carburization process. Applied Catalysis B: Environmental, 239, 463–474. DOI: 10.1016/j.apcatb.2018.08.043
  40. Jongerius, A.L., Gosselink, R.W., Dijkstra, J., Bitter, J.H., Bruijnincx, P.C.A., Weckhuysen, B.M. (2013). Carbon Nanofiber Supported Transition-Metal Carbide Catalysts for the Hydrodeoxygenation of Guaiacol. Chem. Cat. Chem., 5, 2964 – 2972. DOI: 10.1002/cctc.201300280
  41. Grilc, M., Veryasov, G., Likozar, B., Jesih, A., Levec, J. (2015). Hydrodeoxygenation of solvolysed lignocellulosic biomass by unsupported MoS2, MoO2, Mo2C and WS2 catalysts. Applied Catalysis B: Environmental, 163, 467–477. DOI: 10.1016/j.apcatb.2014.08.032
  42. Baddour, F.G., Witte, V.A., Nash, C.P., Griffin, M.B., Ruddy, D.A., Schaidle, J.A. (2017). Late-Transition-Metal-Modified β Mo2C Catalysts for Enhanced Hydrogenation during Guaiacol Deoxygenation. ACS Sustainable Chem. Eng., 5, 11433−11439. DOI: 10.1021/acssuschemeng.7b02544.s001
  43. Fang, H., Du, J., Tian, C., Zheng, J., Duan, X., Ye, L., Yuan, Y. (2017). Regioselective hydrogenolysis of aryl ether C--O bonds by tungsten carbides with controlled phase compositions. Chem. Commun., 53, 10295-10298. DOI: 10.1039/c7cc05487d
  44. Ma, R., Cui, K., Yang, L., Ma, X., Li, Y. (2015). Selective catalytic conversion of guaiacol to phenols over a molybdenum carbide catalyst. Chem. Commun., 51, 10299-10301. DOI: 10.1039/c5cc01900a
  45. Lee, W.-S., Wang, Z., Wu, R.J., Bhan, A. (2014). Selective vapor-phase hydrodeoxygenation of anisole to benzene on molybdenum carbide catalysts. Journal of Catalysis, 319, 44–53. DOI: 10.1016/j.jcat.2014.07.025
  46. Shi, C., Zhu, A.M., Yang, X.F., Au, C.T. (2004). NO reduction with hydrogen over cobalt molybdenum nitride and molybdenum nitride: a comparison study. Catalysis Letters, 97, 9-16. DOI: 10.1023/b:catl.0000034284.53221.71
  47. Kojima, R., Aika, K. (2000). Cobalt Molybdenum Bimetallic Nitride Catalysts for Ammonia Synthesis. Chemistry Letters, 514-515. DOI: 10.1246/cl.2000.514
  48. Zhao, Z., Zou, H., Lin, W. (2013). Effect of rare earth and other cationic promoters on properties of CoMoNx/CNTs catalysts for ammonia decomposition. Journal of rare earths, 31, 247-250. DOI: 10.1016/S1002-0721(12)60266-x
  49. Xu, J., Yan, H., Jin, Z., Jia, C.-J. (2019). Facile Synthesis of Stable MO2N Nanobelts with High Catalytic Activity for Ammonia Decomposition. Chin. J. Chem., 37, 364－372. DOI: 10.1002/cjoc.201900016
  50. Tominaga, H., Nagai, M. (2010). Reaction mechanism for hydrodenitrogenation of carbazole on molybdenum nitride based on DFT study. Applied Catalysis A: General, 389, 195–204. DOI: 10.1016/j.apcata.2010.09.020
  51. Miyata, A., Tominaga, H., Nagai, M. (2010). Active site distribution analysis of hydrodenitrogenation catalyst using Fredholm integral equation. Applied Catalysis A: General, 374, 150–157. DOI: 10.1016/j.apcata.2009.12.004
  52. Jaf, Z.N., Altarawneh, M., Miran, H.A., Jiang, Z.-T., Dlugogorski, B.Z. (2018). Hydrodesulfurization of Thiophene over γ-Mo2N catalyst. Molecular Catalysis, 459, 21–30. DOI: 10.1016/j.mcat.2018.07.008
  53. Gong, S., Chen, H., Li, W., Li, B. (2005). Synthesis of β-Mo2N0.78 hydrodesulfurization catalyst in mixtures of nitrogen and hydrogen. Applied Catalysis A: General, 279, 257–261. DOI: 10.1016/j.apcata.2004.10.038
  54. Wang, H., Yan, S., Salley, S.O., Simon Ng, K.Y. (2012). Hydrocarbon Fuels Production from Hydrocracking of Soybean Oil Using Transition Metal Carbides and Nitrides Supported on ZSM-5. Ind. Eng. Chem. Res., 51, 10066−10073. DOI: 10.1021/ie3000776
  55. Wyvratt, B.M., Gaudet, J.R., Pardue, D.B., Marton, A., Rudic, S., Mader, E.A., Cundari, T.R., Mayer, J.M., Thompson, L.T. (2016). Reactivity of Hydrogen on and in Nanostructured Molybdenum Nitride: Crotonaldehyde Hydrogenation. ACS Catal., 6, 5797−5806. DOI: 10.1021/acscatal.6b01454
  56. Monnier, J., Sulimma, H., Dalai, A., Caravaggio, G. (2010). Hydrodeoxygenation of oleic acid and canola oil over alumina-supported metal nitrides. Applied Catalysis A: General, 382, 176–180. DOI: 10.1016/j.apcata.2010.04.035
  57. Zhang, W., Zhang, Y., Zhao, L., Wei, W. (2010). Catalytic Activities of NiMo Carbide Supported on SiO2 for the Hydrodeoxygenation of Ethyl Benzoate, Acetone, and Acetaldehyde. Energy Fuels, 24, 2052–2059. DOI: 10.1021/ef901222z
  58. Neylon, M.K., Choi, S., Kwon, H., Curry1, K.E., Thompson, L.T. (1999). Catalytic properties of early transition metal nitrides and carbides: n-butane hydrogenolysis, dehydrogenation and isomerization. Applied Catalysis A: General, 183, 253-263. DOI: 10.1016/S0926-860X(99)00053-8
  59. Sajkowski, D.J., Oyama, S.T. (1996). Catalytic hydrotreating by molybdenum carbide and nitride: unsupported Mo2N and Mo2C/Al2O3. Applied Catalysis A: General, 134, 339-349. DOI: 10.1016/0926-860x(95)00202-2
  60. Ruddy, D.A., Schaidle, J.A., Ferrell III, J.R., Wang, J., Moens, L., Hensley, J.E. (2014). Recent advances in heterogeneous catalysts for bio-oil upgrading via "ex situ catalytic fast pyrolysis": catalyst development through the study of model compounds. Green Chem., 16, 454–490. DOI: 10.1039/c3gc41354c
  61. Dabros, T.M.H., Stummann, M.Z., Høj, M., Jensen, P.A., Grunwaldt, J.-D., Gabrielsen, J., Mortensen, P.M., Jensen, A.D. (2018). Transportation fuels from biomass fast pyrolysis, catalytic hydrodeoxygenation, and catalytic fast hydropyrolysis. Progress in Energy and Combustion Science, 68, 268-309. DOI: 10.1016/j.pecs.2018.05.002
  62. Li, C., Zhao, X., Wang, A., Huber, G.W., Zhang, T. (2015). Catalytic Transformation of Lignin for the Production of Chemicals and Fuels. Chem. Rev., 115, 11559−11624. DOI: 10.1021/acs.chemrev.5b00155
  63. Yang, L., Seshan, K., Li, Y. (2017). A review on thermal chemical reactions of lignin model compounds. Catalysis Today, 298, 276–297. DOI: 10.1016/j.cattod.2016.11.030
  64. Mäki-Arvela, P., Murzin, D.Y. (2017). Hydrodeoxygenation of Lignin-Derived Phenols: From Fundamental Studies towards Industrial Applications. Catalysts, 7, 265. DOI: 10.3390/catal7090265
  65. Li, X., Chen, G., Liu, C., Ma, W., Yan, B., Zhang, J. (2017). Hydrodeoxygenation of lignin-derived bio-oil using molecular sieves supported metal catalysts: A critical review. Renewable and Sustainable Energy Reviews, 71, 296–308. DOI: 10.1016/j.rser.2016.12.057
  66. Shafaghat, H., Sirous Rezaei, P., Wan Daud, W.M.A. (2015). Effective parameters on selective catalytic hydrodeoxygenation of phenolic compounds of pyrolysis bio-oil to high-value hydrocarbons. RSC Adv., 5, 103999–104042. DOI: 10.1039/c5ra22137d
  67. Furimsky, E. (2003). Metal carbides and nitrides as potential catalysts for hydroprocessing. Applied Catalysis A: General, 240, 1–28. DOI: 10.1016/S0926-860X(02)00428-3
  68. Volpe, L., Boudart, M. (1985). Compounds of molybdenum and tungsten with high specific surface area: Ⅰ.Nitrides. J. of Solid State Chemistry, 59, 332-347. DOI: 10.1016/0022-4596(85)90301-9
  69. Volpe, L., Boudart, M. (1985). Compounds of molybdenum and tungsten with high specific surface area: Ⅱ.Carbides. J. of Solid State Chemistry, 59, 348-356. DOI: 10.1016/0022-4596(85)90302-0
  70. Zhang, Y., Xin, Q., Rodriguez-Ramos, I., Guerrero-Ruiz, A. (1999). Temperature dependence of the pseudomorphic transformation of MoO3 to γ-Mo2N. Materials Research Bulletin, 34, 145–156. DOI: 10.1016/S0025-5408(98)00200-1
  71. Wise, R.S., Markel, E.J. (1994). Catalytic NH3 Decomposition by Topotactic Molybdenum Oxides and Nitrides: Effect on Temperature Programmed γ-Mo2N Synthesis. J. Catal., 145, 335-343. DOI: 10.1006/jcat.1994.1042
  72. Wise, R.S., Markel, E.J. (1994). Synthesis of High Surface Area Molybdenum Nitride in Mixtures of Nitrogen and Hydrogen. J. Catal., 145, 344-355. DOI: 10.1006/jcat.1994.19021
  73. Claridge, J.B., York, A.P.E., Brungs, A.J., Green, M.L.H. (2000). Study of the Temperature-Programmed Reaction Synthesis of Early Transition Metal Carbide and Nitride Catalyst Materials from Oxide Precursors. Chem. Mater., 12, 132-142. DOI: 10.1021/cm9911060
  74. Zheng, Y., Chen, D., Zhu, X. (2013). Aromatic hydrocarbon production by the online catalytic cracking of lignin fast pyrolysis vapors using Mo2N/-Al2O3. Journal of Analytical and Applied Pyrolysis, 104, 514–520. DOI: 10.1016/j.jaap.2013.05.018
  75. Choi, J.-G., Curl, R.L., Thompson, L.T. (1994). Molybdenum nitrid catalysts: Ⅰ. Influence of the synthesis factors on structural properties. J. Catal., 146, 218-227. DOI: 10.1016/0021-9517(94)90024-8
  76. Podila, S., Zaman, S.F., Driss, H., Al-Zahrani, A.A., Daous, M.A., Petrov, L.A. (2017). High performance of bulk Mo2N and Co3Mo3N catalysts for hydrogen production from ammonia: Role of citric acid to Mo molar ratio in preparation of high surface area nitride catalysts. International Journal of Hydrogen Energy, 42, 8006-8020. DOI: 10.1016/j.ijhydene.2017.01.044
  77. Ghampson, I.T., Sepúlveda, C., Garcia, R., Frederick, B.G., Wheeler, M.C., Escalona, N., DeSisto, W.J. (2012). Guaiacol transformation over unsupported molybdenum-based nitride catalysts. Applied Catalysis A: General, 413–414, 78–84. DOI: 10.1016/j.apcata.2011.10.050
  78. Ghampson, I.T., Sepúlveda, C., Garcia, R., García Fierro, J.L., Escalona, N., DeSisto, W.J. (2012). Comparison of alumina- and SBA-15-supported molybdenum nitride catalysts for hydrodeoxygenation of guaiacol. Applied Catalysis A: General, 435–436, 51–60. DOI: 10.1016/j.apcata.2012.05.039
  79. Sepúlveda, C., Leiva, K., García, R., Radovic, L.R., Ghampson, I.T., DeSisto, W.J., García Fierro, J.L., Escalona, N. (2011). Hydrodeoxygenation of 2-methoxyphenol over Mo2N catalysts supported on activated carbons. Catalysis Today, 172, 232–239. DOI: 10.1016/j.cattod.2011.02.061
  80. Ghampson, I.T., Sepúlveda, C., Garcia, R., Radovic, Lj.R., García Fierro, J.L., DeSisto, W.J., Escalona, N. (2012). Hydrodeoxygenation of guaiacol over carbon-supported molybdenum nitride catalysts: Effects of nitriding methods and support properties. Applied Catalysis A: General, 439–440, 111–124. DOI: 10.1016/j.apcata.2012.06.047
  81. Boullosa-Eiras, S., Lødeng, R., Bergem, H., Stöcker, M., Hannevold, L., Blekkan, E.A. (2014). Catalytic hydrodeoxygenation (HDO) of phenol over supported molybdenum carbide, nitride, phosphide and oxide catalysts. Catalysis Today, 223, 44–53. DOI: 10.1016/j.cattod.2013.09.044
  82. Nagai, M., Tominaga, H., Kai, S. (2013). Active Site Distribution of Nitrided CoMo/Al2O3 Catalyst during Hydrodesulfurization of Dibenzothiophene: A Non-parametric Study. Journal of the Japan Petroleum Institute, 56, 80-87. DOI: 10.1627/jpi.56.80
  83. Li, Y., Zhang, Y., Raval, R., Li, C., Zhai, R., Xin, Q. (1997). The modification of molybdenum nitrides: the effect of the second metal component. Catalysis Letters, 48, 239-245. DOI: 10.1023/a:1019095524872
  84. Bui, V.N., Toussaint, G., Laurenti, D., Mirodatos, C., Geantet, C. (2009). Co-processing of pyrolisis biooils and gas oil for new generation of bio-fuels: Hydrodeoxygenation of guaı¨acol and SRGO mixed feed. Catalysis Today, 143, 172–178. DOI: 10.1016/j.cattod.2008.11.024
  85. Bui, V.N., Laurenti, D., Delichère, P., Geantet, C. (2011). Hydrodeoxygenation of guaiacol Part II: Support effect for CoMoS catalysts on HDO activity and selectivity. Applied Catalysis B: Environmental, 101, 246–255. DOI: 10.1016/j.apcatb.2010.10.025
  86. Centeno, A., Laurent, E., Delmon, B. (1995). Influence of the Support of CoMo Sulfide Catalysts and of the Addition of Potassium and Platinum on the Catalytic Performances for the Hydrodeoxygenation of Carbonyl, Carboxyl, and Guaiacol-Type Molecules. Journal of catalysis, 154, 288-298. DOI: 10.1006/jcat.1995.1170
  87. Liu, X., Xu, L., Xu, G., Jia, W., Ma, Y., Zhang, Y. (2016). Selective Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexanols or Cyclohexanes over Magnetic CoNx@NC Catalysts under Mild Conditions. ACS Catal., 6, 7611−7620. DOI: 10.1021/acscatal.6b01785.s001
  88. Molinari, V., Giordano, C., Antonietti, M., Esposito, D. (2014). Titanium Nitride-Nickel Nanocomposite as Heterogeneous Catalyst for the Hydrogenolysis of Aryl Ethers. J. Am. Chem. Soc., 136, 1758−1761. DOI: 10.1021/ja4119412
  89. Giordano, C., Erpen, C., Yao, W., Milke, B., Antonietti, M. (2009). Metal Nitride and Metal Carbide Nanoparticles by a Soft Urea Pathway. Chem. Mater., 21, 5136–5144. DOI: 10.1021/cm9018953
  90. Molinari, V., Clavel, G., Graglia, M., Antonietti, M., Esposito, D. (2016). Mild Continuous Hydrogenolysis of Kraft Lignin over Titanium Nitride−Nickel Catalyst. ACS Catal., 6, 1663−1670. DOI: 10.1021/acscatal.5b01926.s001
  91. Ma, X., Ma, R., Hao, W., Chen, M., Yan, F., Cui, K., Tian, Y., Li, Y. (2015). Common Pathways in Ethanolysis of Kraft Lignin to Platform Chemicals over Molybdenum-Based Catalysts. ACS Catal., 5, 4803−4813. DOI: 10.1021/acscatal.5b01159
  92. Chen, M., Hao, W., Ma, R., Ma, X., Yang, L., Yan, F., Cui, K., Chen, H., Li, Y. (2017). Catalytic ethanolysis of Kraft lignin to small-molecular liquid products over an alumina supported molybdenum nitride catalyst. Catalysis Today, 298, 9–15. DOI: 10.1016/j.cattod.2017.08.012
  93. Chen, L., Korányi, T.I., Hensen, E.J.M. (2016). Transition metal (Ti, Mo, Nb, W) nitride catalysts for lignin depolymerisation. Chem. Commun., 52, 9375-9378. DOI: 10.1039/c6cc04702e
  94. Song, Q., Wang, F., Cai, J., Wang, Y., Zhang, J., Yu, W., Xu, J. (2013). Lignin depolymerization (LDP) in alcohol over nickelbased catalysts via a fragmentation--hydrogenolysis process. Energy Environ. Sci., 6, 994–1007. DOI: 10.1039/c2ee23741e
  95. Mohan, D., Pittman, Jr., C.U., Steele, P.H. (2006). Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review. Energy & Fuels, 20, 848-889. DOI: 10.1021/ef0502397
  96. Zhang, H., Cheng, Y.-T., Vispute, T.P., Xiao, R., Huber, G.W. (2011). Catalytic conversion of biomass-derived feedstocks into olefins and aromatics with ZSM-5: the hydrogen to carbon effective ratio. Energy Environ. Sci., 4, 2297–2307. DOI: 10.1039/C1EE01230D
  97. Shen, D., Zhao, J., Xiao, R., Gu, S. (2015). Production of aromatic monomers from catalytic pyrolysis of black-liquor lignin. Journal of Analytical and Applied Pyrolysis, 111, 47–54. DOI: 10.1016/j.jaap.2014.12.013
  98. Li, P., Chen, X., Wang, X., Shao, J., Lin, G., Yang, H., Yang, Q., Chen, H. (2017). Catalytic Upgrading of Fast Pyrolysis Products with Fe , Zr , and Co- Modified Zeolites Based on Pyrolyzer−GC/MS Analysis. Energy Fuels, 31, 3979−3986. DOI: 10.1021/acs.energyfuels.6b03105
  99. Sirous Rezaei, P., Shafaghat, H., Wan Daud, W.M.A. (2014). Production of green aromatics and olefins by catalytic cracking of oxygenate compounds derived from biomass pyrolysis: A review. Applied Catalysis A: General, 469, 490–511. DOI: 10.1016/j.apcata.2013.09.036
  100. Jackson, M.A., Compton, D.L., Boateng, A.A. (2009). Screening heterogeneous catalysts for the pyrolysis of lignin. J. Anal. Appl. Pyrolysis, 85, 226–230. DOI: 10.1016/j.jaap.2008.09.016
  101. Mihalcik, D.J., Boateng, A.A., Mullen, C.A., Goldberg, N.M. (2011). Packed-Bed Catalytic Cracking of Oak-Derived Pyrolytic Vapors. Ind. Eng. Chem. Res., 50, 13304–13312. DOI: 10.1021/ie201831e
  102. Lu, Q., Guo, H.-q., Zhou, M.-x., Cui, M.-s., Dong, C.-q., Yang, Y.-p. (2018). Selective preparation of monocyclic aromatic hydrocarbons from catalytic cracking of biomass fast pyrolysis vapors over Mo2N/HZSM-5 catalyst. Fuel Processing Technology, 173, 134–142. DOI: 10.1016/j.fuproc.2018.01.017
  103. Lu, Q., Wang, Z.-x., Guo, H.-q., Li, K., Zhang, Z.-x., Cui, M.-s., Yang, Y.-p. (2019). Selective preparation of monocyclic aromatic hydrocarbons from ex-situ catalytic fast pyrolysis of pine over Ti(SO4)2-Mo2N/HZSM-5 catalyst. Fuel, 243, 88–96. DOI: 10.1016/j.fuel.2019.01.102
  104. Lu, Q., Guo, H.-q., Zhou, M.-x., Zhang, Z.-x., Cui, M.-s., Zhang, Y.-y., Yang, Y.-p., Zhang, L.-b. (2018). Monocyclic aromatic hydrocarbons production from catalytic cracking of pine wood-derived pyrolytic vapors over Ce-Mo2N/HZSM-5 catalyst. Science of the Total Environment, 634, 141–149. DOI: 10.1016/j.scitotenv.2018.03.351
  105. Neylon, M.K., Choi, S., Kwon, H., Curry, K.E., Thompson, L.T. (1999). Catalytic properties of early transition metal nitrides and carbides: n-butane hydrogenolysis, dehydrogenation and isomerization. Applied Catalysis A: General, 183, 253-263. DOI: 10.1016/s0926-860x(99)00053-8
  106. CN102942947-A
  107. US2015209770-A1
  108. CN106244184-A
  109. CN106433807-A

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