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Mathematical Modelling of Catalytic Fixed-Bed Reactor for Carbon Dioxide Reforming of Methane over Rh/Al2O3 Catalyst

1Chemical Reaction Engineering Group (CREG), Faculty of Chemical and Natural Resources Engineering, Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru, Malaysia

2Department of Chemical Engineering, Diponegoro University, Jl. Prof. Sudharto, Kampus Undip Tembalang, Semarang, Indonesia

Received: 20 Aug 2008; Revised: 20 Sep 2008; Accepted: 24 Sep 2008; Published: 15 Dec 2008.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2008 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
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Abstract
A one-dimensional mathematical model was developed to simulate the performance of catalytic fixed bed reactor for carbon dioxide reforming of methane over Rh/Al2O3 catalyst at atmospheric pressure. The reactions involved in the system are carbon dioxide reforming of methane (CORM) and reverse water gas shift reaction (RWGS). The profiles of CH4 and CO2 conversions, CO and H2 yields, molar flow rate and mole raction of all species as well as reactor temperature along the axial bed of catalyst were simulated. In addition, the effects of different reactor temperature on the reactor performance were also studied. The models can also be applied to analyze the performances of lab-scale micro reactor as well as pilot-plant scale reactor with certain modifications and model verification with experimental data. © 2008 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
Keywords: fixed-bed; mass and energy balances; CORM; RWGS; simulation; Rh/Al2O3

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  1. Suhartanto, T., York, A.P.E., Hanif, A., Al-Megren, H. and Green, M.L.H., 2001, Potential Utilisation of Indonesia’s Natuna Natural Gas Field via Methane Dry Reforming to Synthesis Gas, Catal. Lett., 71(1-2): 49-54
  2. Larentis, A.L., de Resende, N.S., Salim, V.M.M. and Pinto, J.C., 2001, Modelling and Optimization of The Combined Carbon Dioxide Reforming and Partial Oxidation of Natural Gas, Appl. Catal. A: Gen., 215: 211-224
  3. Prabhu, A.K., Liu, A., Lovell, L.G. and Oyama, S.T., 2000, Modelling of The Methane reforming Reaction in Hydrogen Selective Membrane Reactors, J. Membr. Sci., 177: 83-95
  4. Froment, G.F., 2000, Production of Synthesis Gas by Steam- and CO2-Reforming of Natural Gas, J. Mol. Catal. A: Chem., 163: 147-156
  5. Mohammadzadeh, J.S.S. and Zamaniyan, A., 2002, Catalyst Shape as a Design Parameter – Optimum Shape for Methane-Steam Reforming Catalyst, Trans. Inst. Chem. Eng. Part A, 80: 383-391
  6. Slamet and Harjito, E., 2001, Kinetic Studies of CH4/CO2 Reforming Reaction over Ni/La2O3 Catalyst Using Integral Reactor, Pros. Sem. Nas. Rekayasa Kimia dan Proses 2001, E-4.1-E-4.7 (in Indonesian)
  7. Fogler, H.S., 1999, Elements of Chemical Reaction Engineering, Prentice-Hall International Inc., Toronto, Canada
  8. Smith, J. M., Van Ness, H. C. and Abbott, M. M., 2001, Introduction to Chemical Engineering Thermodynamics, 6th Ed., McGraw-Hill Inc., Singapore
  9. Krylov, O.V., Mamedov, A.Kh. and Mirzabekova, S.R., 1998, Interaction of Carbon Dioxide with Methane on the Oxide Catalysts, Catal. Today, 42: 211-215
  10. Wang, S., Lu, G.Q.M. and Millar, G.J., 1996, Carbon Dioxide Reforming of Methane to Produce Synthesis Gas over Metal-Supported Catalysts: State of the Art, Energy and Fuel, 10: 896-904

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