Facile Oxidative Desulfurisation of Benzothiophene Using Polyoxometalate H4[α-SiW12O40]/Zr Catalyst

Aldes Lesbani Aldes Lesbani; Agnes Agnes; Randi O. Saragih; Marieska Verawaty; Risfidian Mohadi; Hilda Zulkifli

doi:10.9767/bcrec.10.2.7734.185-191

DOI: https://doi.org/10.9767/bcrec.10.2.7734.185-191

Facile Oxidative Desulfurisation of Benzothiophene Using Polyoxometalate H4[α-SiW12O40]/Zr Catalyst

Aldes Lesbani Aldes Lesbani¹ , Agnes Agnes¹, Randi O. Saragih¹, Marieska Verawaty², Risfidian Mohadi¹, Hilda Zulkifli¹

¹Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Kampus Unsri Inderalaya, Jl. Palembang-Prabumulih Km 32, Ogan Ilir 30662, South Sumatera, Indonesia

²Department of Biology, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Kampus Unsri Inderalaya, Jl. Palembang-Prabumulih Km 32, Ogan Ilir 30662, South Sumatera, Indonesia

Received: 9 Nov 2014; Revised: 31 Mar 2015; Accepted: 23 Apr 2015; Available online: 12 Jul 2015; Published: 30 Aug 2015.

Editor(s): Istadi Istadi

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Fulltext View|Download

Citation Format:

Abstract

A highly active catalyst H4[α-SiW12O40]/Zr based polyoxometalete Keggin type was prepared by wet impregnation method and was characterized by FTIR spectroscopy, X-ray diffractometer, surface textural property by SEM, and analysis of porosity by BET method. H4[α-SiW12O40]/Zr was successfully synthesized and showed uniform properties with block solid structure which was applied as heterogeneous stable catalyst for oxidative desulfurization of benzothiophene under simple and mild condition using H2O2 as oxidant. Facile conversion of benzothiophene to sulfone by using heterogeneus H4[α-SiW12O40]/Zr catalyst up to 99% was observed to show the active catalytically. Keggin H4[α-SiW12O40]/Zr cage structure after reaction was different from fresh catalyst which was indicated by the instability of H4[α-SiW12O40]/Zr under reaction condition. © 2015 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)

Keywords: polyoxometalate; desulfurization; benzothiophene; Keggin type; H4[α-SiW12O40]/Zr

Funding: Ministry of Research and Technology of Indonesia under contract contract No. 64/SEK/INSINAS/PPK/I/2014

Article Metrics:

Article Info

Section: Original Research Articles

Language : EN

In 2015: BCREC Volume 10 Issue 2 Year 2015 (August 2015)

Recent articles

Experimental Study and Kinetic Modeling of Decoking of Pacol Process Dehydrogenation Catalyst Modeling and Simulation of CO2 Absorption into Promoted Aqueous Potassium Carbonate Solution in Industrial Scale Packed Column Application of La-ZSM-5 Coated Silicon Carbide Foam Catalyst for Toluene Methylation with Methanol Backmatter (Publication Ethics, Copyright Transfer Agreement for Publishing Form) Frontmatter (Front Cover, Editorial Team, Indexing, and Table of Contents) Preface, BCREC Vol. 10 No. 2 Year 2015 More recent articles

Wang, D., Qian, E.W., Amano, H., Okata, K., Ishihara, A., Kabe, T. (2003). Oxidative desulfurization of Fuel Oil. Part I. Oxidation of dibenzothiophenes using tert-butyl hydroperoxide, Applied Catalysis A: General, 253: 91-99
Shiraishi, Y., Taki, Y., Hirai, T., Komasawa, I. (2001). A Novel Desulfurization Process for Fuel Oils Based on the Formation and Subsequent Precipitation of S-Alkylsulfonium Salts. 1. Light Oil Feedstocks, Industrial & Engineering Chemistry Research, 40: 1213-1224
Xiao, J., Wu, L., Wu, Y., Liu, B., Dai, L., Li, Z., Xia, Q., Xi, H. (2014). Effect of Gasoline Composition Oxidative Desulfurization Using a Phosphotungstic Acid/Activated Carbon Catalyst With Hydrogen Peroxide, Applied Energy, 113: 78-85
Yu, F-.L., Wang, Y-.Y., Liu, C-.Y., Xie, C-.X., Yu. S-.T. (2014). Oxidative Desulfurization of Fuels Catalyzed by Ammonium Oxidative-Thermoregulated Bifunctional Ionic Liquids, Chemical Engineering Journal, 255: 372-376
Torres-García, E., Galano, A., Rodriguez-Gattorno, G. (2011). Oxidative Desulfurization (ODS) of Organosulfur Compounds Catalyzed by Peroxo-metallate Complexes of WOx-ZrO2: Thermochemical, Structural, and Reactivity Indexes Analyses. Journal of Catalysis, 282: 201-208
Trakarnpruk, W., Rujiraworawut, K. (2009). Oxidative Desulfurization of Gas Oil by Polyoxometalates Catalysts. Fuel Processing Technology, 90: 411-414
Wang, R., Zhang, G., Zhao, H. (2010). Polyoxometalate as Effective Catalyst For the Deep Desulfurization of Diesel Oil. Catalysis Today, 149: 117-121
Reddy, B.M., Patil, M.K. (2008). Promoted Zirconia Solid Acid Catalysts for Organic Synthesis, Current Organic Chemistry, 12: 118-140
Tézé, A., Herve, G. (1990). a-, b-, and g-Dodecatungstosilicic Acids: Isomers and Related Lacunary Compounds. Inorganic Synthesis, 27: 93-94
Devassy, B.M., Halligudi, S.B., Hegde, S.G., Halgeri, A.B., Lefebvre, F. (2002). 12-Tungstophosphoric Acid/Zirconia-a Highly Active Stable Solid Acid-Comparison With a Tungstated Zirconia Catalyst. Chemical Communication. 10: 1074-1075
Uchida, S., Mizuno, M. (2003). Unique Guest-Inclusion Properties of a Breathing Ionic Crystal of K3[Cr3O(OOCH)6(H2O)3[α-SiW12O40]·16H2O. Chemistry A European Journal. 9: 5850-5857
Aouissi, A. (2010). Transformation of n-heptane by Brönsted Acidic Sites Over 12-Tungstosilicic Acid. Asian Journal of Chemistry, 22:4924-4930
Long, Z., Yang, C., Zeng, G., Peng, L., Dai, C., He, H. (2014). Catalytic Oxidative Desulfurization of Dibenzothiophene Using Catalyst of Tungsten Supported on Resin D152, Fuel, 130: 19-24
Xu, J., Li, H., Wang, S., Luo, F., Liu, Y., Wang, X., Jiang, Z. (2014). Ultra-deep Desulfurization Via Reactive Adsorption on peroxophosphomolybdate / agarose Hybrids. Chemosphere, 111: 631-637
Rezvani, M.A., Shojaie, A.F., Loghmani, M.H. (2012). Synthesis and Characterization of Novel Nanocomposite, Anatase Sandwich Type Polyoxometalate, as a Reuseable and Green nano Catalyst in Oxidation Desulfurization of Simulated Gas Oil. Catalysis Communications, 25: 36-40

Last update:

No citation recorded.

Last update:

No citation recorded.

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Journal Author(s) Rights

In order for Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) and BCREC Publishing Group to publish and disseminate research articles, we need non-exclusive publishing rights (transfered from author(s) to publisher). This is determined by a publishing agreement between the Author(s) and Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) and BCREC Publishing Group. This agreement deals with the transfer or license of the right for publishing to Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) and BCREC Publishing Group, while Authors still retain significant all copy rights to use and share their own published articles. Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) and BCREC Publishing Group supports the need for authors to share, disseminate and maximize the impact of their research and these rights, in any databases.

As a journal Author, you have all copy rights for a large range of uses of your article, including use by your employing institute or company. These Author copy rights can be exercised without the need to obtain specific permission. Authors who publishing in BCREC journals have wide copy rights to use their works for teaching and scholarly purposes without needing to seek permission, including, but not limited to:

use for classroom teaching by Author or Author's institution and presentation at a meeting or conference and distributing copies to attendees;
use for internal training by author's company;
distribution to colleagues for their reseearch use;
use in a subsequent compilation of the author's works;
inclusion in a thesis or dissertation;
reuse of portions or extracts from the article in other works (with full acknowledgement of final article);
preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article);
voluntary posting on open web sites operated by author or author’s institution for scholarly purposes,

(but it should follow the open access license of Creative Common CC-by-SA License).

Authors/Readers/Third Parties can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (the name of the creator and attribution parties (authors detail information), a copyright notice, an open access license notice, a disclaimer notice, and a link to the material), provide a link to the license, and indicate if changes were made (Publisher indicates the modification of the material (if any) and retain an indication of previous modifications using a CrossMark Policy and information about Erratum-Corrigendum notification).

Authors/Readers/Third Parties can read, print and download, redistribute or republish the article (e.g. display in a repository), translate the article, download for text and data mining purposes, reuse portions or extracts from the article in other works, sell or re-use for commercial purposes, remix, transform, or build upon the material, they must distribute their contributions under the same license as the original Creative Commons Attribution-ShareAlike (CC BY-SA).

Right Transfer Agreement for Publishing (RTAP)

The Authors submitting a manuscript do so on the understanding that if accepted for publication, non-exclusive right for publishing (publishing right) of the article shall be assigned/transferred to Publisher of Bulletin of Chemical Reaction Engineering & Catalysis journal (Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) and BCREC Publishing Group).

Upon acceptance of an article, authors will be asked to complete a 'Right Transfer Agreement for Publishing (RTAP)'. An e-mail will be sent to the Corresponding Author confirming receipt of the manuscript together with a 'Right Transfer Agreement for Publishing' form by online version of this agreement.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Masyarakat Katalis Indonesia-Indonesian Catalyst Society (MKICS), the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of right for publishing (RTAP), our journal Author(s) still retain (or are granted back) significant scholarly copy rights as mentioned before.

The Right Transfer Agreement for Publishing (RTAP) Form can be downloaded here: [Right Transfer Agreement for Publishing (RTAP) Form BCREC 2025]

The copyright form should be signed electronically and send to the Editorial Office in the form of original e-mail below:

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis
Laboratory of Plasma-Catalysis (R3.5), UPT Laboratorium Terpadu, Universitas Diponegoro
Jl. Prof. Soedarto, Semarang, Central Java, Indonesia 50275
Telp/Whatsapp: +62-81-316426342
E-mail: bcrec[at]live.undip.ac.id ; bcrec[at]che.undip.ac.id

(This policy statements has been updated at 24th January 2024)