DOI: https://doi.org/10.9767/bcrec.13.2.1749.386-392

Simple and Green Adipic Acid Synthesis from Cyclohexanone and/or Cyclohexanol Oxidation with Efficient (NH4)xHyMzPMo12O40 (M: Fe, Co, Ni) Catalysts

1Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria

2Département de Chimie, Faculté des Sciences, Université Mouloud Mammeri (UMMTO), 15000 Tizi Ouzou, Algeria

3ILV-UMR 8180 CNRS, Université de Versailles -St Quent -en-Yvelines, Bâtiment Lavoisier, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France

Received: 12 Nov 2017; Revised: 18 Feb 2018; Accepted: 19 Feb 2018; Available online: 11 Jun 2018; Published: 1 Aug 2018.
Editor(s): Dmitry Yu. Murzin
Open Access Copyright (c) 2018 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.
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Abstract

The oxidation of cyclohexanone and/or cyclohexanol to adipic acid (AA) was performed at 90 °C with a reaction time of 20 h, in the presence of H2O2 as oxidant and transition metal substituted ammonia polyoxometalates of formula, (NH4)xHyMzPMo12O40 (M: Fe, Co, or Ni,  and x = 2.5 or 2.28) as catalysts.  The catalytic results showed that the AA yield is sensitive to the transition metal nature and to the reaction conditions (sample weight and substrate amount). The (NH4)2.29H0.39Co0.16PMo12O40 was found to be the better catalytic system toward AA synthesis from cyclohexanone oxidation, with 40% of AA yield 

Keywords: Keggin mixed salts; Oxidation; Hydrogen peroxide; Cyclohexanone; cyclohexanol; Adipic acid

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