DOI: https://doi.org/10.9767/bcrec.16500

Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste

1Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, Indonesia

2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, Indonesia

3Department of Physics, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, Indonesia

4 Pharmaceutical Department, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, Indonesia

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Received: 19 Nov 2022; Revised: 2 Feb 2023; Accepted: 3 Feb 2023; Available online: 6 Feb 2023; Published: 30 Mar 2023.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2023 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
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Abstract

In this work, the Sumatera bentonite was sodium-pillarized in a new low-temperature and restricted time preparation route and then applied in anionic surfactant sodium lauryl sulphate removal. Structure characterization used Fourier Transform Infra Red (FT-IR), Scanning Electron Microscope - Energy Dispersive X-ray (SEM-EDX), X-ray Diffraction (XRD), and Brunauer–Emmett–Teller (BET) analysis. A strong peak at 22° and 35.66° in XRD analysis was detected as Sodium-pillar that increased crystallinity, then the functional changes of dehydration in lattice structure were detected in 1013 cm−1 by FTIR analysis. The morphology and compositional transformation were analyzed by SEM-EDX and BET analysis, denoted by increasing particle shape and sodium intercalant composition homogeneity. Moreover, the surface area increased from 61.791 to 66.086 m2/g. The sodium lauryl sulphate adsorption by bentonite-Na reached maximum capacity at 8.403 mg/g, which is higher than the pristine bentonite (5.747 mg/g) under the optimum condition. The adsorption mechanism is feasible, endothermic, and conformed to the pseudo-second-order and Freundlich adsorption model. The new route proposed for sodium intercalation effectively improves the Sumatera bentonite adsorption ability to remove sodium lauryl sulphate waste. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

 

Keywords: Pillarization; Sumatera Bentonite; Bentonite-Na; Adsorption; Sodium Lauryl Sulphate.
Funding: Faculty of Mathematics and Natural Sciences, Sriwijaya University

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Section: Original Research Articles
Language : EN
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