skip to main content

Recovery and Utilization of Waste Heat from Cooler Effluent for Preheating Applications

Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Semarang 50275, Indonesia

Received: 12 Dec 2025; Revised: 17 Dec 2025; Accepted: 18 Dec 2025; Available online: 2 Jan 2026; Published: 30 Jun 2026.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2026 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Fulltext View|Download

Citation Format:
Cover Image
Abstract

Maleic anhydride (MA) is an important intermediate for polymers, coatings, and fine chemicals, yet its production through n-butane oxidation remains energy-intensive due to the highly exothermic nature of the reaction. Inefficient heat management leads to excessive utility demand and reduced process performance. This study aims to improve energy efficiency by recovering and reusing waste heat from the cooler effluent for preheating applications. The process is simulated using Aspen HYSYS to compare the basic configuration with a modified design that integrates a recycle stream from the cooler outlet to the heater. The modified configuration demonstrates a significant reduction in external energy consumption, achieving a 43% energy saving compared to the basic process. Net energy decreases markedly, while overall energy efficiency increases to 86%. The recycle stream stabilizes temperature profiles, reduces utility demand, and enhances process reliability. These improvements confirm that waste heat recovery through heat integration provides a practical and effective approach to optimize maleic anhydride production. In conclusion, the modification advances the current state of process design by demonstrating that simple operational changes can deliver substantial energy savings and support sustainable chemical manufacturing. The findings highlight the potential application of waste heat recovery strategies in other exothermic oxidation systems and provide a foundation for future studies on coupling heat integration with advanced separation schemes. Copyright © 2026 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Keywords: Maleic Anhydride; Waste Heat Recovery; Heat Integration; Energy Efficiency; Aspen HYSYS Simulation

Article Metrics:

  1. Asyfianto, M.A., Kristiana, D., Larasati, N.D., Fairuzza, S. (2025). Improving Purity of Maleic Anhydride Production by Multi-stage Distillation. Journal of Chemical Engineering Research Progress, 2 (1), 80-85. DOI: 10.9767/jcerp.20318
  2. Dong, Y., Geske, M., Korup, O., Ellenfeld, N., Rosowski, F., Dobner, C., Horn, R. (2018). What happens in a catalytic fixed-bed reactor for n-butane oxidation to maleic anhydride? Insights from spatial profile measurements and particle resolved CFD simulations. Chemical Engineering Journal, 350, 799-811. DOI: 10.1016/j.cej.2018.05.192
  3. Smith, W.A., Chernyak, Y. (2015). U.S. Patent No. 8,940,915. Washington, DC: U.S. Patent and Trademark Office
  4. Yu, T.Y., Kuo, C.T., Lai, C.K., Won, W., Yu, B.Y. (2024). Unraveling the alternative process configurations for more environmentally friendly Maleic Anhydride production. Process Safety and Environmental Protection, 191, 2385-2401. DOI: 10.1016/j.psep.2024.09.116
  5. Wang, B.J., Dai, F., Jiang, L., Zhang, R., Chu, G.W., Liu, R., Luo, Y. (2023). A vanadium phosphorus oxide catalyst synthesized in rotating packed bed for high‐efficiency selective oxidation of n‐butane. AIChE Journal, 69(1), e17495. DOI: 10.1002/aic.17495
  6. Müller, M., Kutscherauer, M., Böcklein, S., Mestl, G., Turek, T. (2020). Improved kinetics of n-butane oxidation to maleic anhydride: The role of byproducts. Industrial & Engineering Chemistry Research, 60(1), 218-229. DOI: 10.1021/acs.iecr.0c05029
  7. Jouhara, H., Khordehgah, N., Almahmoud, S., Delpech, B., Chauhan, A., Tassou, S.A. (2018). Waste heat recovery technologies and applications. Thermal Science and Engineering Progress, 6, 268-289. DOI: 10.1016/j.tsep.2018.04.017
  8. Zhou, Y., Shi, Y., Liu, Y., Sun, P., Mao, M. (2023). Experimental and simulation research on heat extraction characteristics from a pilot-scale reverse flow reactor for low-grade energy. Applied Thermal Engineering, 220, 119761. DOI: 10.1016/j.applthermaleng.2022.119761
  9. Ortega-Fernández, I., Rodríguez-Aseguinolaza, J. (2019). Thermal energy storage for waste heat recovery in the steelworks: The case study of the REslag project. Applied Energy, 237, 708-719. DOI: 10.1016/j.apenergy.2019.01.007
  10. Cho, K.C., Shin, K.Y., Shim, J., Bae, S.S., Kwon, O.D. (2024). Performance Analysis of a Waste Heat Recovery System for a Biogas Engine Using Waste Resources in an Industrial Complex. Energies, 17(3), 727. DOI: 10.3390/en17030727
  11. Yang, Z., Pan, T., Zhang, N., Smith, R. (2025). Heat exchanger network synthesis with optimal waste heat recovery and multiple hot utilities. Energy, 324, 136011. DOI: 10.1016/j.energy.2025.136011
  12. Varga, Z., Palotai, B. (2017). Comparison of low temperature waste heat recovery methods. Energy, 137, 1286-1292. DOI: 10.1016/j.energy.2017.07.003
  13. Iftinan, H.N., Andari, C.N., Khotimah, D.K., Husna, H.I. (2025). Improving Energy Efficiency with Reusage Outlet Stream of Heat Exchanger for Formaldehyde Production from Methanol. Journal of Chemical Engineering Research Progress, 2(1), 72-79. DOI: 10.9767/jcerp.20313

Last update:

No citation recorded.

Last update:

No citation recorded.