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Improving Product Purity of Ethylene Glycol Production from Ethylene Oxide by Modify Process Using Multi-stage Distillation

Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Semarang 50275, Indonesia

Received: 11 Dec 2025; Revised: 17 Dec 2025; Accepted: 17 Dec 2025; Available online: 30 Dec 2025; Published: 30 Jun 2026.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2026 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
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Abstract

Ethylene glycol (EG) is an important industrial chemical widely used in the manufacture of polyester fibers, antifreeze formulations, and heat-transfer fluids. Industrially, EG is produced through the hydration of ethylene oxide; however, achieving high product purity remains a significant challenge due to the presence of water and higher glycols in the reaction mixture. This study proposes a process modification aimed at improving ethylene glycol purity through the implementation of a multi-stage distillation system. The conventional single-stage distillation configuration was evaluated and compared with a modified two-stage distillation scheme. Simulation results indicate that the proposed modification significantly enhances separation performance, increasing ethylene glycol mole fraction from 0.8991 in the unmodified process to 0.9990 in the modified configuration. The improvement is attributed to better distribution of separation duties and enhanced control of vapor–liquid equilibrium across multiple distillation stages. These findings demonstrate that multi-stage distillation, supported by rigorous process simulation, is an effective strategy for producing high-purity ethylene glycol and offers valuable insights for industrial process optimization and design. Copyright © 2026 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Keywords: Ethylene glycol; Energy Consumption; Energy Efficient

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  1. Othman, J., Rahman, N.A., Ali, J. M., Kamarudin, S.K. (2025). Intensification of high-purity mono ethylene glycol production. Jurnal Kejuruteraan, 37(6), 2667–2679. DOI: 10.17576/jkukm-2025-37(6)-16
  2. Ali, A.O., Mohammed, A.A., Abuuznien, M.H.M. (2020). Simulation of ethylene glycol production from used ethylene oxide in sterilization of syringes. World Journal of Engineering Research and Technology, 6(1), 135-144
  3. Zaboon S. (2017). Recovery of mono-ethylene glycol by distillation and the analysis of packed column operation performance. Procedia Engineering, 184, 299–306. DOI: 10.1016/j.proeng.2017.04.099
  4. Chen W., Ding, Y., Wang, F., Xu, Z., Ye, Q., Li, J., Paricaud, P. (2025). Separation of ethylene glycol and ethylene glycol diacetate azeotropic mixture with a heterogeneous extraction distillation process. Separation and Purification Technology, 362, 131645. DOI: 10.1016/j.seppur.2024.131645
  5. Liu, X.-W. (2016). Advances in methods for separation of ethylene glycol and 1,2-butanediol. 36, 16–19 and 21. DOI: 10.16606/j.cnki.issn0253-4320.2016.09.004
  6. Cortes Garcia, G.E., van der Schaaf, J., Kiss, A.A. (2017). A review on process intensification in HiGee distillation. Journal of Chemical Technology and Biotechnology, 92(6), 1136–1156. DOI: 10.1002/jctb.5157
  7. Garin, M., Adiguna, E., Suprapto. (2022). Optimization of ethylene glycol plant heat exchanger network with non-catalytic hydration process from ethylene oxide. IPTEK Journal of Engineering, 8(2), 56–64. DOI: 10.12962/j23373539.v8i2.14072
  8. Moghaddam, A.H., Esfandyari, M. (2025). Optimization of separation and purification processes in diethyl ether production for improved efficiency and sustainability. Scientific Reports, 15, Article 27911. DOI: 10.1038/s41598-025-77911-4
  9. Iregbu, F., Okwu, P.O., Agbara, K.C., Ademiluyi, J.O. (2025). Design and Optimization of a 45,000 Tonne/Year Ethylene Glycol Production Plant Using ASPEN HYSYS. International Research Journal of Advanced Engineering and Science, 10(2), 80–83
  10. Sitio, A.R.H., Azahra, D.S., Zahrani, F.N., Martantri, R.Z.M., Ajitira, S.N. (2024). Maximizing Ethylene Production Yield by Modifying the Methanol to Olefin Process with the Addition of a Distillation Tower. Journal of Chemical Engineering Research Progress, 1(2), 200–209. DOI: 10.9767/jcerp.20278
  11. Taqvi, S.A., Tufa, L.D., Muhadizir, S. (2016). Optimization and Dynamics of Distillation Column Using Aspen Plus®. In Procedia Engineering (Vol. 148, pp. 978–984). DOI: 10.1016/j.proeng.2016.06.484
  12. Aryaputra, B.M., Safitri, A.N., Razita, D.K., Setyani, S.H.P., Mulfiana, A.Z. (2025). Enhancing the yield and mass production of vinyl chloride production from ethylene and chloride through EDC vapor recovery in direct chlorination process. Journal of Chemical Engineering Research Progress, 2(1), 51–60. DOI: 10.9767/jcerp.20310
  13. Munir, M.T., Yu, W., Young, B.R. (2016). Determination of plantwide control loop configuration and eco-efficiency. In G. P. Rangaiah & V. Kariwala (Eds.), Plant-Wide Control: Recent Developments and Applications (pp. 441–456). John Wiley & Sons. DOI: 10.1002/9781119968962.ch20
  14. Ragab Mahmoud, A. (2025). Thermodynamics in Chemical Reactions: Entropy, Enthalpy, and Free Energy. Shorouk Academy – Department of Engineering
  15. Martínez, J., Zúñiga-Hinojosa, M.A., Ruiz-Martínez, R.S. (2022). A thermodynamic analysis of naphtha catalytic reforming reactions to produce high-octane gasoline. Processes, 10(2), 313. DOI: 10.3390/pr10020313
  16. Yahaya, Suleiman. (2025). Kinetic and thermodynamic modeling of heterogeneous catalysis in biomass conversion for renewable energy production. International Research Journal of Modernization in Engineering Technology and Science, 07. 2582-5208
  17. Umenweke, G.C., Afolabi, I.C., Epelle, E.I., Okolie, J.A. (2022). Machine learning methods for modeling conventional and hydrothermal gasification of waste biomass: A review. Bioresource Technology Reports, 17, 100976. DOI: 10.1016/j.biteb.2022.100976
  18. Tamargo, J., Rosano, G. (2020). Low-quality of some generic medicinal products represents a matter for growing concern. European Heart Journal - Cardiovascular Pharmacotherapy, 6(3), 176-178. DOI: 10.1093/ehjcvp/pvz037/5566494
  19. Singh, D.K., Sharma, S., Thakur, A., Kumar, S., Singh, S. (2018). Pharmaceutical Analysis — Drug Purity Determination. In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 1-12. DOI: 10.1016/B978-0-12-409547-2.14551-2

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