DOI: https://doi.org/10.9767/bcrec.13.1.975.1-6

Synthesis, Structure, and Catalytic Activity of A New Mn(II) Complex with 1,4-Phenylenediacetic Acid and 1,10-Phenanthroline

1College of Information and Engineering, Weifang University, Weifang 261061, China

2College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China

Received: 5 Mar 2017; Revised: 7 Jun 2017; Accepted: 12 Jul 2017; Available online: 22 Jan 2018; Published: 2 Apr 2018.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2018 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.
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Abstract

A new Mn(II) complex material has been synthesized by one-pot reaction of Mn(CH3COO)2·4H2O, 1,4-phenylenediacetic (H2L), 1,10-phenanthroline (phen), and NaOH in water/ethanol (v:v = 1:1) solution. The structure of Mn(II) complex was determined by elemental analysis, FTIR, and X-ray single-crystal diffraction analysis. The results reveal that Mn(II) complex was constructed by a monodentate 1,4-phenylenediacetate ligand, two phen ligands, a coordinated water molecule, 0.5 uncoordinated 1,4-phenylenediacetate ligand and six uncoordinated water molecules. The complex molecules form 1D chain structure by the π-π interaction of phen molecules. The catalytic activity of Mn(II) complex for coupling of benzaldehyde, phenylacetylene and piperidine in 1,4-dioxane has also been  investigated  and the maximum yield of propargylamine is up to 72.2 % after 12 h at 120 oC. 

Keywords: Mn(II) complex; Phenanthroline; Catalytic activity; Mn(II) complex
Funding: National Natural Science Foundation of China under contract No. 21171132 ; Natural Science Foundation of Shandong under contract ZR2014BL003); Project of Shandong Province Higher Educational Science and Technology Program under contract J14LC01; Science Foundation of Weifang

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Section: Original Research Articles
Language : EN
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