Carbon Dioxide Adsorption by Calcium Zirconate at Higher Temperature

K. B. Kale; R. Y. Raskar; V. H. Rane; A. G. Gaikwad

doi:10.9767/bcrec.7.2.3686.124-136

DOI: https://doi.org/10.9767/bcrec.7.2.3686.124-136

Carbon Dioxide Adsorption by Calcium Zirconate at Higher Temperature

K. B. Kale, R. Y. Raskar, V. H. Rane, A. G. Gaikwad

CE & PD Division, National Chemical Laboratory, Pune 411 008, India

Received: 23 Jun 2012; Revised: 28 Aug 2012; Accepted: 30 Aug 2012; Published: 30 Dec 2012.

Editor(s): Istadi Istadi

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

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BibTex Citation Data :

@article{BCREC19576,
    author = {K. B. Kale and R. Y. Raskar and V. H. Rane and A. G. Gaikwad},
    title = {Carbon Dioxide Adsorption by Calcium Zirconate at Higher Temperature},
    journal = {Bulletin of Chemical Reaction Engineering & Catalysis},
  volume = {7},
    number = {2},
    year = {2012},
    keywords = {Calcium zirconate; CO2 adsorption; effect of mol ratio; post- and pre-combustion temperature; sol-gel method},
    abstract = { The CO  2   adsorption by     calcium zirconate was explored at pre- and post- combustion temperature condition. The several samples of the calcium zirconate were prepared by different methods such as sol-gel, solid-solid fusion, template and micro-emulsion. The samples of the calcium zirconate were characterized by measurement of surface area, alkalinity/acidity, and recording the XRD patterns and SEM images. The CO  2   adsorptions by samples of the calcium zirconate were studied in the temperature range 100 to 850   o  C and the CO  2   adsorptions were observed in the ranges of 6.88 to 40.6 wt % at 600   0  C and 8 to 16.82 wt% at in between the temperatures 200 to 300   o  C. The effect of Ca/Zr mol ratio in the samples of the calcium zirconate on the CO  2   adsorption and alkalinity were discussed. The adsorbed moisture by the samples of the calcium zirconate was found to be useful for the CO  2   adsorption. The promoted the samples of the calcium zirconate by K  +  , Na  +  , Rb  +  , Cs  +  , Ag  +   and La  3+   showed the increased CO  2   adsorption. The exposure time of CO  2   on the samples of the calcium zirconate showed the increased CO  2   adsorption. The samples of the calcium zirconate were found to be regenerable and reusable several times for the adsorption of CO  2   for at the post- and pre-combustion temperature condition.  © 2012 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (  https://creativecommons.org/licenses/by-sa/4.0  )  },
   issn = {1978-2993},   pages = {124--136}  doi = {10.9767/bcrec.7.2.3686.124-136},
    url = {https://journal.bcrec.id/index.php/bcrec/article/view/19576}
}

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Abstract

The CO2 adsorption by calcium zirconate was explored at pre- and post- combustion temperature condition. The several samples of the calcium zirconate were prepared by different methods such as sol-gel, solid-solid fusion, template and micro-emulsion. The samples of the calcium zirconate were characterized by measurement of surface area, alkalinity/acidity, and recording the XRD patterns and SEM images. The CO2 adsorptions by samples of the calcium zirconate were studied in the temperature range 100 to 850 oC and the CO2 adsorptions were observed in the ranges of 6.88 to 40.6 wt % at 600 0C and 8 to 16.82 wt% at in between the temperatures 200 to 300 oC. The effect of Ca/Zr mol ratio in the samples of the calcium zirconate on the CO2 adsorption and alkalinity were discussed. The adsorbed moisture by the samples of the calcium zirconate was found to be useful for the CO2 adsorption. The promoted the samples of the calcium zirconate by K+, Na+, Rb+, Cs+, Ag+ and La3+ showed the increased CO2 adsorption. The exposure time of CO2 on the samples of the calcium zirconate showed the increased CO2 adsorption. The samples of the calcium zirconate were found to be regenerable and reusable several times for the adsorption of CO2 for at the post- and pre-combustion temperature condition. © 2012 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)

Keywords: Calcium zirconate; CO2 adsorption; effect of mol ratio; post- and pre-combustion temperature; sol-gel method

Funding: CSIR India under contract the net work project NWP0021

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Section: Original Research Articles

Language : EN

In 2012: BCREC Volume 7 Issue 2 Year 2012 (December 2012)

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