skip to main content

Improving Net Energy Efficiency of Dimethyl Ether Production Process by Methanol Dehydration

Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Indonesia

Received: 20 Dec 2023; Revised: 8 Jan 2024; Accepted: 9 Jan 2024; Available online: 15 Jan 2024; Published: 30 Jun 2024.
Editor(s): Istadi Istadi, Teguh Riyanto
Open Access Copyright (c) 2024 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Fulltext View|Download

Citation Format:
Cover Image
Abstract

Dimethyl ether (DME) is a source of fuel that produces clean energy for the future. Methanol can be used as a raw material for the manufacture of DME as a natural gas that is treated for synthesis. This paper evaluates how to improve net energy efficiency in DME production and how to review the net energy efficiency calculations in DME production. Methods used for production of DME are methanol dehydration, thermodynamics examination, also improving the net energy efficiency of DME with the addition of the heat exchanger (E-100), the addition of a heater (E-104) before entering a column (T-102), and moved the mixer position before the heater (E-100). By modifying the addition of a heat exchanger (E-100), heater (E-104), and changing the position of the mixer in DME production, it has been proven that it can reduce energy requirements in the dimethyl ether synthesis process from methanol and increase net energy efficiency by up to 98.83%. The results of the case study indicate that the addition heat exchanger (E-100) able to reduce the heater load after the creation process and remove the cooler (E-101) that existed before creation, then the addition of the heater (E-104) serves to reduce the load of Qcond2 and Qreb2 on columns (T-102), also the position of the mixer for the methanol recycling flow is moved before the heater (E-100) is intended to remove the heaters (E-103). Copyright © 2024 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Supporting Information (SI) PDF
Keywords: Dimethyl ether; methanol; dehydration; net energy; efficiency

Article Metrics:

  1. Al-Qadri, A.A., Nasser, G.A., Adamu, H., Muraza, O., Saleh, T.A. (2023). CO2 utilization in syngas conversion to dimethyl ether and aromatics: Roles and challenges of zeolites-based catalysts. Journal of Energy Chemistry, 79, 418–449. DOI: 10.1016/j.jechem.2022.12.037
  2. Liu, C., Liu, Z. (2022). Perspective on CO2 hydrogenation for dimethyl ether economy. Catalysts, 12 (11), 1375. DOI: 10.3390/catal12111375
  3. Soltic, P., Hilfiker, T., Wright, Y., Hardy, G., Fröhlich, B., Klein, D. (2024). The potential of dimethyl ether (DME) to meet current and future emissions standards in heavy-duty compression-ignition engines. Fuel, 355, 129357. DOI: 10.1016/j.fuel.2023.129357
  4. Mondal, U., Yadav, G.D. (2019). Perspective of dimethyl ether as fuel: Part I. catalysis. Journal of CO2 Utilization, 32, 299–320. DOI: 10.1016/j.jcou.2019.02.003
  5. Rutkowska, M., Macina, D., Mirocha-Kubien, N., Piwowarska, Z., Chmielarz, L. (2015). Hierarchically structured ZSM-5 obtained by desilication as new catalyst for DME synthesis from methanol, Appl. Catal. B Environ. 174–175, 336–343, DOI: 10.1016/j.apcatb.2015.03.006
  6. Dieterich, V., Buttler, A., Hanel, A., Spliethoff, H., Fendt, S. (2020) Power-to-liquid via synthesis of methanol, DME or Fischer–Tropsch-fuels: a review, Energy Environ. Sci. 13, 3207–3252, DOI: 10.1039/d0ee01187h
  7. Lotfollahzade Moghaddam, A., Hazlett, M.J. (2023). Methanol dehydration catalysts in direct and indirect dimethyl ether (DME) production and the beneficial role of DME in energy supply and environmental pollution. Journal of Environmental Chemical Engineering, 11(3), 110307. DOI: 10.1016/j.jece.2023.110307
  8. Peinado, C., Liuzzi, D., Sluijter, S.N., Skorikova, G., Boon, J., Guffanti, S., Groppi, G., Rojas, S. (2024). Review and perspective: Next generation DME synthesis technologies for the energy transition. Chemical Engineering Journal, 479, 147494. DOI: 10.1016/j.cej.2023.147494
  9. Alshbuki, E.H., Bey, M.M., Mohamed, A. Ala. (2020). Simulation production of dimethylether (DME) from dehydration of methanol using aspen Hysys. Scholars International Journal of Chemistry and Material Sciences, 03(02), 13–18. DOI: 10.36348/sijcms.2020.v03i02.002
  10. Minh, L.Q., Van Duc Long, N., Lee, M. (2012). Energy efficiency improvement of dimethyl ether purification process by utilizing dividing wall columns. Korean Journal of Chemical Engineering, 29 (11), 1500–1507. DOI: 10.1007/s11814-012-0048-6
  11. Zhang, C., Jun, K., Kwak, G., Kim, S. (2018). Energy‐efficient methanol to dimethyl ether processes combined with water‐containing methanol recycling: Process simulation and energy analysis. Energy Technology, 7(1), 167–176. DOI: 10.1002/ente.201800469
  12. Zhang, Q., Qian, X., Fu, L., Yuan, M., Chen, Y. (2020). Shock wave evolution and overpressure hazards in partly premixed gas deflagration of DME/LPG blended multi-clean fuel. Fuel, 268, 117368. DOI: 10.1016/j.fuel.2020.117368
  13. Buchori, L., Anggoro, D.D. (2021). Reaction Kinetics Study of Methanol Dehydration for Dimethyl Ether (DME) Production Using Dealuminated Zeolite Y CatalystReaction Kinetics Study of Methanol Dehydration for Dimethyl Ether (DME) Production Using Dealuminated Zeolite Y Catalyst. Chemical Engineering Transactions. 86, 1501-1506, DOI: 10.3303/CET2186251
  14. Ardy, A., Pohan, R.D., Rizkiana, J., Laniwati, M., Susanto, H. (2019). Dehydration of methanol to dimethyl ether (DME): Performance of three types of catalyst at atmospheric pressure. AIP Conference Proceedings. 2085 (1), 020064, DOI: 10.1063/1.5095042
  15. Turton, R., Joseph A.S., Debangsu B. (2018). Analysis, Synthesis, and Design of Chemical Processes. Prentice Hall: London
  16. Poirier, K., Lotfi, M., Garg, K., Patchigolla, K., Anthony, E.J., Faisal, N.H., Mulgundmath, V., Sahith, J.K., Jadhawar, P., Koh, L., Morosuk, T., Al Mhanna, N. (2023). A comprehensive review of pre- and post-treatment approaches to achieve sustainable desalination for different water streams. Desalination, 566, 116944. DOI: 10.1016/j.desal.2023.116944
  17. Dobladez, J.A., Maté, V.I., Torrellas, S.Á., Larriba, M., Pascual Muñoz, G., Alberola Sánchez, R. (2021). Comparative simulation study of methanol production by CO2 hydrogenation with 3A, 4A and 5A zeolites as adsorbents in a PSA reactor. Separation and Purification Technology, 262, 118292. DOI: 10.1016/j.seppur.2020.118292
  18. Yaws, C.L. (1999). Chemical Properties Handbook. McGraw-Hill

Last update:

No citation recorded.

Last update:

No citation recorded.