DOI: https://doi.org/10.9767/bcrec.12.2.773.281-286

Synthesis of SnO2 Nanoparticles by High Potential Electrolysis

Chemistry Department, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Surabaya 60111, Indonesia

Received: 15 Nov 2016; Revised: 26 Feb 2017; Accepted: 27 Feb 2017; Available online: 8 May 2017; Published: 1 Aug 2017.
Editor(s): Istadi Istadi, Yuly Kusumawati
Open Access Copyright (c) 2017 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.
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Abstract

SnO2 nanoparticles have been synthesized by high voltage electrolysis. Tin bare was used for anode and cathode. The effect of potentials and electrolyte were studied. The particles obtained after electrolysis was characterized using X-ray Diffraction (XRD). The diffractogram is in agreement with the standard diffraction pattern of SnO2 which is identified as tetragonal structure. The Fourier Transform Infrared (FTIR) spectrum indicates that there is a vibration of Sn–O asymmetric at 580 cm-1. The optimum potential for SnO2 nanoparticles synthesis is 60 V at 0.06 M HCl which shows the highest UV-Vis spectrum. The absorption peak of SnO2 nanoparticles by UV-Vis spectrophotometer appears at about 207 nm. The particle size analysis shows that the SnO2 nanoparticles obtained have the size distribution in a range of 25-150 nm with the highest volume at 83.11 nm. 

Keywords: SnO2 nanoparticles; electrochemical; hydrochloric acid; high potential

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Section: The 2nd International Seminar on Chemistry (ISoC 2016) (Surabaya, 26-27 July 2016)
Language : EN
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