skip to main content

New Dynamic Analysis and System Identification of Biodiesel Production Process from Palm Oil

Chemical & Petroleum Engineering Department, University of Sedaya, Kuala Lumpur, Malaysia

Received: 12 Nov 2009; Revised: 20 Dec 2009; Accepted: 27 Dec 2009; Published: 30 Dec 2009.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2009 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Fulltext View|Download

Citation Format:
Abstract
In this study we present advanced mathematical model was used to capture the batch reactor characteristics of reacting compounds new parameters and new a prerequisite average slope analysis (PASA) method for the system dynamic behaviour under different operational conditions is a prerequisite to the good selection for these parameters. The model was applied to batch reactor for the production of bio-diesel from palm and kapok oils. Results of the model were compared with experimental data in terms of conversion of transesterification reaction for the production of bio-diesel under unsteady state. A good agreement was obtained between our model predictions and the experimental data. Both experimental and modeling results showed that the conversion of triglycerides to methyl ester was affected by the process conditions and by using PASA that could be achieved by making some deterministic tests either in real data plant or in the physical model that properly and adequately fits the actual process. The input-output relationships are studied using the open-loop dynamic response of the process, which can be determined from the process model by stepping different inputs and recording output responses. Starting from steady state conditions, each input is perturbed with certain magnitude that is enough to show the effect on the system dynamics. The transesterficition process with temperature of about 70 oC, and methanol ratio to the triglyceride of about 5 times its stoichiometry and the NAOH catalyst of wt 0.4%, appear to be acceptable process conditions. PASA shows methanol ratio to the triglyceride has big effect on the system. PASA method can be applied for different processes. © 2009 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
Keywords: Mathematical model; System identification; Vegetable oil; Catalytic reactor; Dynamic study

Article Metrics:

  1. Ahmmed S Ibrehem, and Hikmat S Al-Salim. Advanced Mathematical Model to Describe the Production of Bio-diesel Process, Bulletin of Chemical Reaction Engineering & Catalysis, Article Inpress, 2009
  2. Clark,S.,J.,Wagner, L., Schrock, M.D., and Pinnaar,P.G.1984.Methyl and ethyl esters as renewable fules for diesel engines. J. Amer. Oil Chem. Soc.,61,1632-1638
  3. Legowo, E.2001,Experience in Palm Biodiesel uses for Transportation, Proceedings of the International Biodiesel Workshop, Medan, Indonesia
  4. Mittelbach and Tritthart, P.1988.Diesel fuel derived from vegetable oils, III Emission test using methyl esters of used frying oils J. Amer. Oil Chem. Soc., 65, 1185-1187
  5. Muniyappa, P.R.,Brammer, S.C., and Noureddini,H.1996.Improved conversion of plant oils and animal fats into biodiesel and co-product, Biodiesel Technology, 56,19-24
  6. Pakpahan,A.2001. Palm Biodiesel: Its potency, technology, business prospect and environmental implication in Indonesian, Proceeding of the International Biodiesel Workshop, medan, Indonesia
  7. Antaresti. et.al., 2005. The Biodiesel Production Process from Vegetable Oil, Dev. Chem. Eng. Mineral Process. 13(5/6), pp.687-692,2005
  8. Dunn, R.O. 2008. Effect of temperature on oil stability index (OSI) of biodiesel. Energy and Fuels. 22:657-662
  9. Gaia Franceschini and Sandro Macchietto, Validation of a Model for a Biodiesel Production Process through Model-Based Experiment Design for Parameter Precision, Computers and Chemical Engineering, 24, 1261-1267
  10. SAE Technical Paper series no. 831356. SAE International Off Highway Meeting, Milwaukee, Wisconsin, USA, 1983

Last update:

No citation recorded.

Last update:

No citation recorded.