DOI: https://doi.org/10.9767/bcrec.13.2.1178.220-226

Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand

1College of Information and Engineering, Weifang University, Weifang 261061, China

2College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China

Received: 25 Apr 2017; Revised: 11 Sep 2017; Accepted: 1 Nov 2017; Available online: 11 Jun 2018; Published: 1 Aug 2018.
Editor(s): Dmitry Yu. Murzin
Open Access Copyright (c) 2018 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.
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Abstract

A new Cd(II) coordination polymer, {[Cd3(L)2(DMF)2(H2O)2]·H2O}n (H2L = 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid) was synthesized by one-pot synthesis method from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid, NaOH, DMF, and Cd(NO3)2·4H2O. Its structure was determined by elemental analysis and single crystal X-ray diffraction. Structural analysis shows that three Cd(II) ions are all six-coordinated with four oxygen atoms of four 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands and two O atoms from two DMF molecules (Cd1) or two oxygen atoms of two coordinated H2O molecules (Cd2 and Cd3) to form an octahedral coordination geometry. The Cd(II) coordination polymer displays a 1D chained structure by the bridging carboxylate groups from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands. The conversion of benzaldehyde is 90.9%, which is 40~50% higher than those of the other three aldehydes (4-methylbenzaldehyde, p-methoxybenzaldehyde and 3-chlorobenzaldehyde), so the Cd(II) coordination polymer catalyst shows better catalytic activity for the coupling reaction of benzaldehyde, phenylacetylene, and piperidine than the other three aldehydes. 

Keywords: 1,3-Bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid; Cd(II) coordination polymer; Synthesis; Structural characterization; Catalytic property
Funding: the Science Foundation of Weifang

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Section: Original Research Articles
Language : EN
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